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Synthesis of Selenium-Containing Humic Nano-Biocomposites from Sodium Bis(2-phenylethyl)phosphinodiselenoate

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Abstract

New water-soluble selenium-containing nano-biocomposites have been synthesized by oxidation of sodium bis(2-phenylethyl)phosphinodiselenoate with hydrogen peroxide using humic substances to stabilize selenium nanoparticles. As shown by a set of physicochemical methods, the obtained hybrid nanocomposites are formed as spherical hexagonal selenium particles with a size of 13–30 nm, dispersed in a humic matrix.

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Funding

This study was performed under partial financial support by the Russian Foundation for Basic Research (project no. 18-316-20017mol_a_ved, synthesis of selenium-containing nanocomposites) in the framework of state assignment for Irkutsk Institute of Chemistry (project nos. AAAA-A19-119022690046-4, AAAA-A16-116112510011-8).

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, 664033, Russia

    M. V. Lesnichaya, G. P. Aleksandrova, S. F. Malysheva, N. A. Belogorlova & B. G. Sukhov

  2. Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, 664033, Russia

    A. N. Sapozhnikov

  3. Institute of Chemistry and Chemical Technology, Academy of Sciences of Mongolia, Ulan-Bator, 210351, Mongolia

    G. Dolmaa

Authors
  1. M. V. Lesnichaya
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  2. G. P. Aleksandrova
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  3. S. F. Malysheva
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  4. N. A. Belogorlova
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  5. A. N. Sapozhnikov
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  6. G. Dolmaa
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  7. B. G. Sukhov
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Corresponding author

Correspondence to M. V. Lesnichaya.

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Conflict of Interest

No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2020, published in Zhurnal Obshchei Khimii, 2020, Vol. 90, No. 1, pp. 157–164.

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Lesnichaya, M.V., Aleksandrova, G.P., Malysheva, S.F. et al. Synthesis of Selenium-Containing Humic Nano-Biocomposites from Sodium Bis(2-phenylethyl)phosphinodiselenoate. Russ J Gen Chem 90, 123–128 (2020). https://doi.org/10.1134/S1070363220010193

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