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Sequential Interaction of Enamine with O, O-Dialkyldithiophosphoric Acid and Electrophilic Reagent

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Abstract

The adduct of O, O-dialkyldithiophosphoric acid and enamine reacts exothermically with an electrophilic reagent. In the case of sulfenyl bromide, the iminium salt reduced at the C-Br bond and bis(dialkoxythiophosphorylthio)-disulfide have been formed, experimentally evidencing the reaction of 2-halogenated ald- and ketimines with dithioic acid via the intermediate formation of enamine.

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Funding

This study was financially supported by the Ministry of Education and Science of Russian Federation in the scope of the basic part of the State Task in the field of research activity (project no. 4.5348.2017/8.9).

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Authors and Affiliations

  1. Kazan National Research Technological University, Kazan, 420015, Russia

    R. A. Khairullin, M. B. Gazizov, Yu. S. Kirillina, S. Yu. Ivanova & L. P. Shamsutdinova

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  1. R. A. Khairullin
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  2. M. B. Gazizov
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  3. Yu. S. Kirillina
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  4. S. Yu. Ivanova
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  5. L. P. Shamsutdinova
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Corresponding author

Correspondence to M. B. Gazizov.

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Conflict of Interest

No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2020, published in Zhurnal Obshchei Khimii, 2020, Vol. 90, No. 1, pp. 111–116.

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Khairullin, R.A., Gazizov, M.B., Kirillina, Y.S. et al. Sequential Interaction of Enamine with O, O-Dialkyldithiophosphoric Acid and Electrophilic Reagent. Russ J Gen Chem 90, 84–88 (2020). https://doi.org/10.1134/S1070363220010120

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  • DOI: https://doi.org/10.1134/S1070363220010120

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