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Reversible Rearrangements of 2,4,6-Trinitrophehyl Group in an Amidine System

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Abstract

Tautomeric 1,3-N, N′-migrations of 2,4,6-trinitrophenyl group in the derivatives of N, N′-diarylbenzamidine and N, N′-diarylformamidine have been studied by quantum-chemical simulations using the B3LYP/6-311++G(d, p) method of density functional theory.

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Funding

This study was performed in the scope of the State Task from the Ministry of Education and Science Russia (project no. 4.979.2017/4.6) and Southern Research Center of Russian Academy of Sciences (state registration no. 01201354239).

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Authors and Affiliations

  1. Institute of Physical and Organic Chemistry of Southern Federal University, Rostov-on-Don, 344090, Russia

    G. A. Dushenko, I. E. Mikhailov & V. I. Minkin

  2. Federal Research Center “Southern Scientific Center of the Russian Academy of Science,”, Rostov-on-Don, 344006, Russia

    I. E. Mikhailov

Authors
  1. G. A. Dushenko
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  2. I. E. Mikhailov
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  3. V. I. Minkin
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Corresponding author

Correspondence to G. A. Dushenko.

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Conflict of Interest

No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2020, published in Zhurnal Obshchei Khimii, 2020, Vol. 90, No. 1, pp. 10–17.

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Dushenko, G.A., Mikhailov, I.E. & Minkin, V.I. Reversible Rearrangements of 2,4,6-Trinitrophehyl Group in an Amidine System. Russ J Gen Chem 90, 7–12 (2020). https://doi.org/10.1134/S1070363220010028

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  • DOI: https://doi.org/10.1134/S1070363220010028

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