Abstract
S-Methyl diethylphosphinothioate reacted with benzylidene chlorides to give the corresponding aryl(chloro)methyl methyl sulfide and diethylphosphinoyl chloride. The product structure suggests initial attack of the methylsulfanyl group on the CH carbon atom of dichloromethylarene. Arenecarbothialdehyde dithioacetals and trimers and O,O-dialkyl[aryl(methylsulfanyl)methyl]phosphonates were synthesized.
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Funding
This study was performed under financial support by the Ministry of Science and Higher Education of the Russian Federation in the framework of the base part of state assignment in the sphere of research activity (project no. 4.5348.2017/BCh).
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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 12, pp. 1869–1873.
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Gazizov, M.B., Valieva, G.D., Ivanova, S.Y. et al. Reactions of Benzylidene Chlorides with S-Methyl Diethylphosphinothioate. Russ J Gen Chem 89, 2386–2389 (2019). https://doi.org/10.1134/S1070363219120107
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DOI: https://doi.org/10.1134/S1070363219120107