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Manganese and Iron Complexes with Malonic Acid Bis[2-(3,5-di-tert-butyl-2-hydroxybenzyl)hydrazide]

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Abstract

New manganese(II) and iron(III) complexes with hydrazones derived from malonic acid dihydrazide and 3,5-di-tert-butylsalicylaldehyde have been synthesized. The structure of the complexes has been studied by IR and electronic spectroscopy and X-ray analysis. Malonic acid bis[(2-hydroxy-3,5-di-tert-butylbenzylidene)-hydrazide] has been shown to form dinuclear complexes with manganese and iron ions, in which ferromagnetic interaction between the metal ions is observed.

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Authors and Affiliations

  1. Nagiev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

    P. A. Fatullaeva

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  1. P. A. Fatullaeva
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Correspondence to P. A. Fatullaeva.

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No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 8, pp. 1269–1273.

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Fatullaeva, P.A. Manganese and Iron Complexes with Malonic Acid Bis[2-(3,5-di-tert-butyl-2-hydroxybenzyl)hydrazide]. Russ J Gen Chem 89, 1649–1652 (2019). https://doi.org/10.1134/S1070363219080164

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  • DOI: https://doi.org/10.1134/S1070363219080164

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