Russian Journal of General Chemistry

, Volume 89, Issue 8, pp 1620–1624 | Cite as

Synthesis of 1,3,3,5,5-Penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-[(1H-1,2,3-triazol-4-yl)alkoxy]cyclotriphosphazenes

  • V. P. MorgalyukEmail author
  • T. S. Strelkova
  • Yu. N. Kononevich
  • V. K. Brel


Based on 1,3,3,5,5-penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-chlorocyclotriphosphazene, a series of hybrid compounds was obtained by two-step synthesis. In the molecules of the compounds obtained, hydrophobic organic residues are attached to the cyclotriphosphazene nucleus via a linker. A dialkyl substituted 1,2,3-triazole synthesized by click-chemistry methodology from acetylenic cyclotriphosphazene derivatives and organic azides in the presence of Cu(I) can be used as a linker connecting pentadioxolane-substituted phosphazene core. The reaction proceeds regioselectively with the formation of 1,4-disubstituted 1,2,3-triazoles only.


1,3,3,5,5-penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-chlorocyclotriphosphazene click-chemistry 1,2,3-triazole acetylenes organic azides 


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This work was supported by the Russian Foundation for Basic Research (grant no. 18-03-00275) and the Ministry of Science and Higher Education of the Russian Federation using the scientific equipment of the Center for Molecular Structure Research of the Institute of Organoelement Compounds of the Russian Academy of Sciences.


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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. P. Morgalyuk
    • 1
    Email author
  • T. S. Strelkova
    • 1
  • Yu. N. Kononevich
    • 1
  • V. K. Brel
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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