Russian Journal of General Chemistry

, Volume 89, Issue 6, pp 1332–1337 | Cite as

Study of the Adsorption Activity of Skeletal Nickel with Respect to Reactive Hydrogen by Simultaneous Thermal Analysis Mass Spectrometry

  • D. A. ProzorovEmail author
  • A. V. Afineevskii
  • N. N. Smirnov
  • Y. P. Sukhachev
  • M. D. Chelysheva


A method for the determination of the total amounts and physical parameters of adsorbed individual hydrogen species on the surface and in the bulk of metal catalysts of liquid-phase hydrogenation reactions by simultaneous thermal analysis mass spectrometry was proposed. The adsorptions of reactive hydrogen on a skeletal nickel catalyst in an aqueous medium were estimated. The concentrations of metal-hydrogen complexes with different binding energies on the surface of the catalyst in the liquid phase were determined by a direct experimental method.


concentration of adsorbed hydrogen reactive hydrogen nickel catalyst simultaneous thermal analysis mass spectrometry 


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  1. 1.
    Boreskov, G.K., Geterogennyi kataliz (Heterogeneous Catalysis), Moscow: Nauka, 1986), p. 3.Google Scholar
  2. 2.
    Prozorov, D. A. and Lukin, M.V., Vestn. Tver. Gos. Univ., Ser. Khim., 2013, no. 15, p. 168.Google Scholar
  3. 3.
    Problems of Thermodynamics of Surface Phenomena and Adsorption, Koifman, O.I. and Ulitin, M.V., Eds., Ivanovo: Ivan. Gos. Khim.-Tekhnol, Univ., 2009, p. 256.Google Scholar
  4. 4.
    Problemy termodinamiki poverkhnostnykh yavlenii i adsorbtsii (Problems of Thermodynamics of Surface Phenomena and Adsorption), Ulitin, M.V. and Koifman, O.I., Ivanovo: Ivan. Gos. Khim.-Tekhnol, Univ., 2005, p. 212.Google Scholar
  5. 5.
    Ryazanov, M.A., Russ. J. Phys. Chem. A, 2012, vol. 86, no. 4, p. 664. doi CrossRefGoogle Scholar
  6. 6.
    Barbov, A.V., Shepelev, M.V., Filippov, D.V., and Ulitin, M.V., Russ. J. Phys. Chem. A, 2010, vol. 84, no. 9, p. 1605. doi CrossRefGoogle Scholar
  7. 7.
    Afineevskii, A.V. and Lukin, M.V., Abstracts of Papres, 4 Nauchnaya konferentsiya “Fizicheskaya khimiya poverkhnostnykh yavlenii i adsorbtsii” (4th Scientific Conf. “Physical Chemistry of Surface Phenomena and Adsorption”), Ivanovo: Ivan. Gos. Khim.-Tekhnol, Univ., 2013, p. 4.Google Scholar
  8. 8.
    Korosteleva, P.O., Ulitin, M.V., Lukin, M.V., and Filippov, D.V., Russ. J. of Phys. Chem. A, 2009, vol. 83, no. 10, p. 1715. doi CrossRefGoogle Scholar
  9. 9.
    Ulitin, M.V., Barbov, A.V., Shalukhin, V.G., and Gostikin V.P., Russ. J. Appl. Chem., 1993, vol. 66, no. 3, p. 497.Google Scholar
  10. 10.
    Barbov, A.V., Nabilkov, V.E., and Ulitin, M.V., Russ. J. Phys. Chem., 1997, vol. 71, no. 3, p. 367.Google Scholar
  11. 11.
    Afineevskii, A.V., Prozorov, D.A., Lukin, M.V., and Ulitin, M.V., Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 2010, vol. 53, no. 9, p. 18.Google Scholar
  12. 12.
    Ulitin, M.V. Trunov, A.A., Lefedova, O.V., and Barbov, A.V., Russ. J. Phys. Chem., 1998, vol. 72, no. 12, p. 2010.Google Scholar
  13. 13.
    Afineevskii, A.V., Prozorov, D.A., and Smirnov, N.N., Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 2015, vol. 58, no. 2, p. 83.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • D. A. Prozorov
    • 1
    Email author
  • A. V. Afineevskii
    • 1
  • N. N. Smirnov
    • 1
  • Y. P. Sukhachev
    • 1
  • M. D. Chelysheva
    • 1
  1. 1.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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