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Approaches to the Control of Morphological Parameters of Inorganic Nanoparticles in the Synthesis from Solutions

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Abstract

General regularities of nanoparticles formation from solutions under various conditions (organic and aqueous media, mild and rigid conditions) are presented and analyzed. Two ways of a a solid phase formation, based on simultaneous or sequential crystallization, are proposed; examples of the corresponding synthetic procedures are given. The process of sequential crystallization is described. The ability to reduce or increase particle sizes by using morphology control agents has been demonstrated by specific examples. Nucleating agents or nuclei can be successfully used to reduce the size of particles or to obtain the desired crystalline phases (if the compound is characterized by several polymorphs).

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7-9, St. Petersburg, 199034, Russia

    O. M. Osmolovskaya, Yu. V. Petukhova, A. A. Podurets, E. A. Syukkalova, V. V. Suslonov, D. S. Kolokolov, S. V. Kotel’nikova, N. P. Bobrysheva & M. G. Osmolowsky

Authors
  1. O. M. Osmolovskaya
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  2. Yu. V. Petukhova
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  3. A. A. Podurets
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  4. E. A. Syukkalova
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  5. V. V. Suslonov
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  6. D. S. Kolokolov
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  7. S. V. Kotel’nikova
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  8. N. P. Bobrysheva
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  9. M. G. Osmolowsky
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Corresponding author

Correspondence to O. M. Osmolovskaya.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 6, pp. 937–945.

Funding

This work was financially supported by the Russian Foundation for Basic Research (grants nos. 18-03-01066-a, 16-03-00167-a, and 13-03-00943-a) with the use of equipment of the resource centers “Chemical Analysis and Materials Research Centre,” “Centre for X-ray Diffraction Studies,” “Center for Optical and Laser Materials Research,” “Centre for Physical Methods of Surface Investigation,” “Centre for Innovative Technologies of Composite Nanomaterials,” “Nanophotonics Centre,” “Magnetic Resonance Research Centre,” “Cryogen sector,” and “Chemistry Educational Centre” of St. Petersburg State University.

Conflict of Interest

No conflict of interest was declared by the authors.

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Osmolovskaya, O.M., Petukhova, Y.V., Podurets, A.A. et al. Approaches to the Control of Morphological Parameters of Inorganic Nanoparticles in the Synthesis from Solutions. Russ J Gen Chem 89, 1154–1161 (2019). https://doi.org/10.1134/S1070363219060094

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  • DOI: https://doi.org/10.1134/S1070363219060094

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