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Russian Journal of General Chemistry

, Volume 89, Issue 5, pp 865–869 | Cite as

Synthesis of Geminally Activated 4-(Furan-2-yl)- and 4-(Thiophen-2-yl)-1-nitrobuta-1,3-dienes

  • R. I. Baichurin
  • A. A. Reshetnikov
  • V. D. Sergeev
  • N. I. Aboskalova
  • S. V. MakarenkoEmail author
Article
  • 17 Downloads

Abstract

The condensation of 3-(furan-2-yl)- and 3-(thiophen-2-yl)prop-2-enals with nitro-substituted CH acids, namely ethyl nitroacetate, nitroacetone, nitroacetophenone, and nitroacetonitrile, afforded a series of geminally activated nitro dienes, 4-(furan-2-yl)- and 4-(thiophen-2-yl)-1-nitrobuta-1,3-dienes. The product structure was confirmed by NMR and IR spectroscopy.

Keywords

ethyl nitroacetate nitroacetone nitroacetophenone nitroacetonitrile 

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Supplementary material

11176_2019_3739_MOESM1_ESM.pdf (1.1 mb)
Method for the synthesis of geminally activated 1-nitro-4-(2-furyl/2-thienyl)-1,3-butadienes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • R. I. Baichurin
    • 1
  • A. A. Reshetnikov
    • 1
  • V. D. Sergeev
    • 1
  • N. I. Aboskalova
    • 1
  • S. V. Makarenko
    • 1
    Email author
  1. 1.Herzen State Pedagogical University of RussiaSt. PetersburgRussia

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