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Synthesis of New Sulfolanopyrazolidines

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Abstract

3-Aryl-6a-methyl-6-nitrohexahydrothieno[2,3-d]pyrazole-4,4-dioxides, new representatives of original bicyclic structures combining fused pyrazolidine and sulfolane rings in a molecule, were obtained through the reactions of 2-benzylidene-3-methyl-4-nitro-3-thiolene-1,1-dioxide and its substituted analogues with hydrazine. Structure of the bicycles obtained was established on the basis of a comprehensive analysis of IR, 1H, 13C{1H}, 1H-13C HMQC, 1H-13C HMBC spectroscopy data, and quantum-chemical calculations.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, nab. reki Moiki 48, St. Petersburg, 191186, Russia

    I. E. Efremova & A. V. Serebryannikova

  2. St. Petersburg State Institute of Technology (Technical University), St. Petersburg, Russia

    A. V. Belyakov

  3. S.M. Kirov Military Medical Academy, St. Petersburg, Russia

    L. V. Lapshina

Authors
  1. I. E. Efremova
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  2. A. V. Serebryannikova
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  3. A. V. Belyakov
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  4. L. V. Lapshina
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Correspondence to I. E. Efremova.

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Efremova, I.E., Serebryannikova, A.V., Belyakov, A.V. et al. Synthesis of New Sulfolanopyrazolidines. Russ J Gen Chem 89, 536–539 (2019). https://doi.org/10.1134/S1070363219030277

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  • DOI: https://doi.org/10.1134/S1070363219030277

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