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Russian Journal of General Chemistry

, Volume 89, Issue 3, pp 536–539 | Cite as

Synthesis of New Sulfolanopyrazolidines

  • I. E. EfremovaEmail author
  • A. V. Serebryannikova
  • A. V. Belyakov
  • L. V. Lapshina
Letters to the Editor
  • 29 Downloads

Abstract

3-Aryl-6a-methyl-6-nitrohexahydrothieno[2,3-d]pyrazole-4,4-dioxides, new representatives of original bicyclic structures combining fused pyrazolidine and sulfolane rings in a molecule, were obtained through the reactions of 2-benzylidene-3-methyl-4-nitro-3-thiolene-1,1-dioxide and its substituted analogues with hydrazine. Structure of the bicycles obtained was established on the basis of a comprehensive analysis of IR, 1H, 13C{1H}, 1H-13C HMQC, 1H-13C HMBC spectroscopy data, and quantum-chemical calculations.

Keywords

sulfolanes pyrazolidines bicycles hydrazine nucleophilic addition aza-Michael reaction 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • I. E. Efremova
    • 1
    Email author
  • A. V. Serebryannikova
    • 1
  • A. V. Belyakov
    • 2
  • L. V. Lapshina
    • 3
  1. 1.Herzen State Pedagogical University of RussiaSt. PetersburgRussia
  2. 2.St. Petersburg State Institute of Technology (Technical University)St. PetersburgRussia
  3. 3.S.M. Kirov Military Medical AcademySt. PetersburgRussia

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