Alkyl 3-Bromo-3-nitroacrylates in Reactions with Aliphatic Alcohols

Russian Journal of General Chemistry volume 89, pages532–535(2019)Cite this article

Abstract

The reactions of alkyl 3-bromo-3-nitroacrylates with aliphatic alcohols at reflux led to the formation of O-adducts—alkyl 2-alkoxy-3-bromo-3-nitropropanoates isolated as mixtures of diastereomers; their structure was proved using 1H, 13C-{1H} NMR, and IR spectroscopy methods.

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Affiliations

  1. Herzen State Pedagogical, University of Russia, nab. r. Moiki 48, St. Petersburg, 191186, Russia

    S. V. Makarenko, V. V. Pelipko, M. M. Pavchenko & R. I. Baichurin

Authors
  1. S. V. Makarenko
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  2. V. V. Pelipko
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  3. M. M. Pavchenko
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  4. R. I. Baichurin
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Correspondence to S. V. Makarenko.

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Makarenko, S.V., Pelipko, V.V., Pavchenko, M.M. et al. Alkyl 3-Bromo-3-nitroacrylates in Reactions with Aliphatic Alcohols. Russ J Gen Chem 89, 532–535 (2019). https://doi.org/10.1134/S1070363219030265

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Keywords

  • nitroacrylates
  • alcohols
  • nucleophilic addition
  • diastereomers
  • diastereotopy