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Synthesis of Bimetallic Pt-W Particles in Autoclave

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Abstract

A possibility of obtaining bimetallic Pt-W particles in an autoclave at 190°C in an alkaline solution was shown. Structure of the obtained particles was studied by dynamic light scattering and X-ray phase analysis. A possible route for the reduction of platinum and tungsten in the selected conditions to the metallic state with ammonia in statu nascendi was proposed.

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References

  1. Ellert, O.G., Codikov, M.V., Nikolaev, S.A., and Novotortsev, V.M., Russ. Chem. Rev., 2014, vol. 83, no. 8, p. 718. 10.1070/RC2014v083n08ABEH004432

    Article  CAS  Google Scholar 

  2. Sankar, M., Dimetratos, N., Miedziak, P.J., Wells, P., Keely, C., and Hutchings, G., Chem. Soc. Rev., 2012, vol. 41, p. 8099. doi 10.1039/c2cs35296f

    Article  CAS  Google Scholar 

  3. Lihui, Ou, Comp. Theor. Chem., 2014, vol. 1048, p. 69. doi 10.1016/j.comptc.2014.09.017

    Article  CAS  Google Scholar 

  4. Wei, Z., Sun, J., Li, Y., Datye, A.K., and Wang, Y., Chem. Soc. Rev., 2012, vol. 41, p. 7994. doi 10.1039/C2CS35201J

    Article  CAS  PubMed  Google Scholar 

  5. Belousov, O.V., Borisov, R.V., Parfenov, V.A., Dorokhova, L.I., and Zharkov, S.M., Russ. J. Phys. Chem. (A), 2012, vol. 86, no. 3, p. 484. doi 10.1134/S0036024412020070

    Article  CAS  Google Scholar 

  6. Stytsenko, V.D. and Mel’nikov, D.P., Russ. J. Phys. Chem. (A), 2016, vol. 90, no. 5, p. 932. doi 10.7868/S0044453716040300

    Article  CAS  Google Scholar 

  7. Grinberg, V.A., Kulova, T.L., Maiorova, N.A., Dobrokhotova, Zh.V., Pasynskii, A.A., Skudin, A.M., and Khazova O.A., Russ. J. Electrochem., 2007, vol. 43, no. 1, p. 75. doi 10.1134/S1023193507010119

    Article  CAS  Google Scholar 

  8. Meza, D., Morales, U., Roquero, P., and Salgado, L., Int. J. Hydr. Energy, 2010, vol. 35, no. 21, p. 12111. doi 10.1016/j.ijhydene.2009.07.021

    Article  CAS  Google Scholar 

  9. Dai, Y., Liu, Y., and Chen, S., Electrochim. Acta, 2013,vol. 89, p. 744. doi 10.1016/j.electacta.2012.11.011

    Google Scholar 

  10. Wang, J., Lei, N., Yang, Ch., Su, Y., Zhao, X., and Wang, A., Chin. J. Catal., 2016, vol. 37, no. 9, p. 1513. doi 10.1016/S1872-2067(16)62479-8

    Article  CAS  Google Scholar 

  11. Mikhailova, A.A., Pasynskii, A.A., Dobrokhotova, Zh.V., Grinberg, V.A., and Khazova, O.A., Russ. J. Electrochem., 2008, vol. 44, no. 3, p. 303. doi 10.1007/s11175-008-3007-0

    Article  CAS  Google Scholar 

  12. Diagrammy sostoyaniya dvoinykh metallicheskikh sistem (Phase Diagrams of Binary Metal Systems), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 1997, vol. 3.

  13. Blagorodnye metally (Noble Metals), Savitskii, E.M., Ed., Moscow: Metallurgiya, 1984.

  14. Sarbak, Z. and Andersson, S.L.T., Stud. Surf. Sci. Catal., 2000, vol. 130, p. 3777.

    Article  Google Scholar 

  15. Belousov, O.V., Sirotina, A.V., Belousova, N.V., Fesik, E.V., Borisov, R.V., and Malchikov, G.D., J. Sib. Federal Univ. Engin. & Technol., 2014, vol. 2, no. 7, p. 138.

    Google Scholar 

  16. Fesik, E.V., Buslayeva, T.M., and Mel’nikova, T.I., Russ. J. Gen. Chem., 2017, vol. 87, no. 2, p. 159. doi 10.1134/S1070363217020013

    Article  CAS  Google Scholar 

  17. Borisov, R.V., Belousov, O.V., Zhizhaev, A.M., and Dorokhova, L.I., J. Sib. Federal Univ. Chem., 2015, vol. 8, no. 3, p. 377. doi 10.17516/1998-2836-2015-8-3-377-385

    Article  Google Scholar 

  18. Borisov, R.V., Belousov, O.V., Zhizhaev, A.M., Belousova, N.V., and Kirik, S.D., Russ. J. Inorg. Chem., 2018, vol. 63, no. 3, p. 303. doi 10.7868/S0044457X18030030

    Article  Google Scholar 

  19. Zarazhevskii, V.I., Grebnev, V.V., Fesik, E.V., and Mal’chikov, G.D., Russ. J. Gen. Chem., 2008, vol. 78, no. 11, p. 1997. doi 10.1134/S1070363208110017

    Article  CAS  Google Scholar 

  20. Bokii, G.B., Kristallokhimiya (Crystal Chemistry), Moscow: Nauka, 1971.

    Google Scholar 

  21. Luo, H.L., J. Less-Com. Met., 1968, vol. 15, p. 299.

    Article  CAS  Google Scholar 

  22. Boultif, A. and Louer, D., J. Appl. Crystallogr., 2004, vol. 37, p. 724. doi 10.1107/S0021889804014876

    Article  CAS  Google Scholar 

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Correspondence to E. V. Fesik.

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Russian Text © E.V. Fesik, T.M. Buslaeva, T.I. Melnikova, 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 2, pp. 319–323.

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Fesik, E.V., Buslaeva, T.M. & Melnikova, T.I. Synthesis of Bimetallic Pt-W Particles in Autoclave. Russ J Gen Chem 89, 309–312 (2019). https://doi.org/10.1134/S1070363219020221

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  • DOI: https://doi.org/10.1134/S1070363219020221

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