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Russian Journal of General Chemistry

, Volume 89, Issue 2, pp 173–184 | Cite as

Physico-Chemical Bases of BaBiO3 Perovskite Synthesis

  • N. V. BarkovskiiEmail author
Article
  • 24 Downloads

Abstract

The physico-chemical basis of optimal conditions for synthesis of BaBiO3 oxide, free from impurities of BaBiO3 and BaBiO3−x oxygen-deficient phases, is given. The reduction of time of the melt contact with a crucible makes it possible to obtain BaBiO3 samples minimum polluted by a crucible material. It was found that an abnormal behavior of BaBiO3 in the course of long-time annealing in air at 450°C is caused by the interaction with CO2.

Keywords

BaBiO3 oxide oxygen-deficient phases valence state X-ray diffraction chemical analysis 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Institute of Solid State PhysicsRussian Academy of SciencesChernogolovkaRussia

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