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Physico-Chemical Bases of BaBiO3 Perovskite Synthesis

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Abstract

The physico-chemical basis of optimal conditions for synthesis of BaBiO3 oxide, free from impurities of BaBiO3 and BaBiO3−x oxygen-deficient phases, is given. The reduction of time of the melt contact with a crucible makes it possible to obtain BaBiO3 samples minimum polluted by a crucible material. It was found that an abnormal behavior of BaBiO3 in the course of long-time annealing in air at 450°C is caused by the interaction with CO2.

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  1. Institute of Solid State Physics, Russian Academy of Sciences, ul. Akademika Osipyana 2, Chernogolovka, 142432, Russia

    N. V. Barkovskii

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Russian Text © N.V. Barkovskii, 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 2, pp. 167–180.

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Barkovskii, N.V. Physico-Chemical Bases of BaBiO3 Perovskite Synthesis. Russ J Gen Chem 89, 173–184 (2019). https://doi.org/10.1134/S1070363219020014

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