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Monolayers of Supramolecular Cryptate Complexes at the Electrode/Solution Interface

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Abstract

The results of investigation of the electrochemical properties of cryptand 222 from the macropolycyclic ligands group and its complexes with cations were summarized. Emphasis was placed on the properties of the adsorbed layers of these substances at the electrode/solution interface. Adsorption parameters of the compounds studied were calculated in the framework of the Frumkin–Damaskin theory of adsorption of organic substances using the regression analysis. Comparative analysis of the data obtained was carried out.

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Authors and Affiliations

  1. Lomonosov Moscow State University, Moscow, 119991, Russia

    E. V. Stenina & L. N. Sviridova

  2. Interdepartmental Center for Analytical Research in Physics, Chemistry, and Biology at Presidium of the Russian Academy of Sciences, Profsoyuznaya ul. 65, Moscow, 117342, Russia

    V. F. Stenin

Authors
  1. E. V. Stenina
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  2. L. N. Sviridova
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  3. V. F. Stenin
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Corresponding authors

Correspondence to E. V. Stenina, L. N. Sviridova or V. F. Stenin.

Additional information

Original Russian Text © E.V. Stenina, L.N. Sviridova, V.F. Stenin, 2016, published in Rossiiskii Khimicheskii Zhurnal, 2016, Vol. 60, No. 3, pp. 40–48.

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Stenina, E.V., Sviridova, L.N. & Stenin, V.F. Monolayers of Supramolecular Cryptate Complexes at the Electrode/Solution Interface. Russ J Gen Chem 88, 2708–2716 (2018). https://doi.org/10.1134/S1070363218120411

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  • DOI: https://doi.org/10.1134/S1070363218120411

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