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Synthesis, Structure, and X-Ray Photoelectron Spectra of Cobalt and Copper Complexes with 2-{(E)-[2-(4-Hydroxybutylamino)benzimidazol-1-yl]iminomethyl}phenol

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Abstract

A new azomethine compound, 2-{(E)-[2-(4-hydroxybutylamino)benzimidazol-1-yl]iminomethyl}- phenol, and its cobalt(II) and copper(II) complexes were synthesized and characterized by IR, 1Н NMR, and X-ray photoelectron spectroscopy and quantum-chemical calculations. The crystal and molecular structures of the cobalt complex were established by X-ray diffraction analysis. The oxidation state of the cobalt ion in the complex after its crystallization from the solution was defined more exactly by X-ray photoelectron spectroscopy.

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Correspondence to V. G. Vlasenko.

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Original Russian Text © V.G. Vlasenko, A.S. Burlov, T.A. Kuz’menko, A.T. Kozakov, A.V. Nikol’skii, A.L. Trigub, S.I. Levchenkov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 12, pp. 2034–2043.

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Vlasenko, V.G., Burlov, A.S., Kuz’menko, T.A. et al. Synthesis, Structure, and X-Ray Photoelectron Spectra of Cobalt and Copper Complexes with 2-{(E)-[2-(4-Hydroxybutylamino)benzimidazol-1-yl]iminomethyl}phenol. Russ J Gen Chem 88, 2550–2558 (2018). https://doi.org/10.1134/S1070363218120150

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