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Study of the Kinetics of Esterification of Dichloromaleic Anhydride with Methanol in the Presence of Zeolitic Catalysts

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Abstract

Kinetics and mechanism of esterification of dichloromaleic anhydride with C1–C4 alcohols in the presence of zeolitic catalysts have been studied. The stage-by-stage Langmuir–Hinshelwood mechanism of heterogeneous catalysis at acidic active surface sites of zeolites has been suggested. The kinetic model has been elaborated, the parameters of the experimental data fitting have been calculated.

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Authors and Affiliations

  1. Nagiev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, pr. G. Dzhavida 113, Baku, Az1143, Azerbaijan

    I. G. Melikova, A. D. Efendi, B. A. Ismailova, G. M. Faradzhev, L. G. Magerramova & K. I. Gadzhieva

Authors
  1. I. G. Melikova
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  2. A. D. Efendi
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  3. B. A. Ismailova
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  4. G. M. Faradzhev
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  5. L. G. Magerramova
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  6. K. I. Gadzhieva
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Corresponding author

Correspondence to I. G. Melikova.

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Original Russian Text © I.G. Melikova, A.D. Efendi, B.A. Ismailova, G.M. Faradzhev, L.G. Magerramova, K.I. Gadzhieva, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 12, pp. 1960–1966.

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Melikova, I.G., Efendi, A.D., Ismailova, B.A. et al. Study of the Kinetics of Esterification of Dichloromaleic Anhydride with Methanol in the Presence of Zeolitic Catalysts. Russ J Gen Chem 88, 2480–2485 (2018). https://doi.org/10.1134/S1070363218120058

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  • DOI: https://doi.org/10.1134/S1070363218120058

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