Abstract
Alkaline hydrolysis of N,N-disubstituted О,О-dialkyl (aminomethyl)phosphonates gives rise to the corresponding О-alkyl (aminomethyl)phosphonic acids. The reaction of potassium О-alkyl (aminomethyl)-phosphonates with organyl halides involves quaternization of the nitrogen atom to form dipolar aminophosphoryl compounds, aminophosphabetaines.
References
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Dedicated to the 115th anniversary of B.A. Arbuzov’s birth
Original Russian Text © A.R. Garifzyanov, N.V. Davletshina, L.I. Akhmadullina, I.T. Safiullin, R.A. Cherkasov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 11, pp. 1923–1926.
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Garifzyanov, A.R., Davletshina, N.V., Akhmadullina, L.I. et al. Synthesis of New Aminophosphabetaines. Russ J Gen Chem 88, 2445–2448 (2018). https://doi.org/10.1134/S1070363218110324
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DOI: https://doi.org/10.1134/S1070363218110324