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Synthesis of Bisthiacalix[4]arene: Reaction of Piperazine with Monoacrylamide Derivative of p-tert-Butylthiacalix[4]arene

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Abstract

The reaction of acryloyl chloride with the monoamine derivative of p-tert-butylthiacalix[4]arene was used to synthesize p-tert-butylthiacalix[4]arene monoacrylamide in the 1,3-alternate conformation. The effect of the nature of the amine on the result of its Michael reaction with the synthesized p-tert-butylthiacalix[4]arene monoacrylamide was studied. The latter was reacted with piperazine to obtain bisthiacalix[4]arene with the macrocyclic fragments in the 1,3-alternate conformation.

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Authors and Affiliations

  1. Butlerov Chemical Institute, Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    R. V. Nosov & I. I. Stoikov

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  1. R. V. Nosov
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  2. I. I. Stoikov
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Correspondence to I. I. Stoikov.

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Dedicated to the 115th anniversary of B.A. Arbuzov’s birth

Original Russian Text © R.V. Nosov, I.I. Stoikov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 11, pp. 1837–1843.

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Nosov, R.V., Stoikov, I.I. Synthesis of Bisthiacalix[4]arene: Reaction of Piperazine with Monoacrylamide Derivative of p-tert-Butylthiacalix[4]arene. Russ J Gen Chem 88, 2314–2320 (2018). https://doi.org/10.1134/S1070363218110117

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  • DOI: https://doi.org/10.1134/S1070363218110117

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