Abstract
The coordination of zinc(II) tetraphenylporphine with pyridines was studied by electronic spectroscopy. Linear correlations were found between the thermodynamic and kinetic parameters of coordination in different solvents. The effect of the solvent on the stability constants of the complexes and the thermodynamics of complex formation are discussed.
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Original Russian Text © V.P. Andreev, P.S. Sobolev, D.O. Zaitsev, S.M. Timofeeva, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 10, pp. 1665–1670.
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Andreev, V.P., Sobolev, P.S., Zaitsev, D.O. et al. Effect of the Solvent on the Coordination of Pyridine Derivatives with Zn Tetraphenylporphine. Russ J Gen Chem 88, 2108–2113 (2018). https://doi.org/10.1134/S1070363218100134
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DOI: https://doi.org/10.1134/S1070363218100134