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β-Elimination in 1,1,1-Trichloro-2,2-bis(4-nitrophenyl)ethane by the Action of Sodium Nitrite in Dipolar Aprotic Solvents

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Abstract

The kinetics of dehydrochlorination of 1,1,1-trichloro-2,2-bis(4-nitrophenyl)ethane with sodium nitrite in dipolar aprotic solvents have been studied. Quantum chemical simulation of the process has been performed, and its thermodynamic parameters have been determined. The effects of dissociation and solvation on the rate constant have been considered. The reaction mechanism has been identified as E2H.

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Authors and Affiliations

  1. Demidov Yaroslavl State University, ul. Sovetskaya 14, Yaroslavl, 150003, Russia

    E. A. Guzov, V. N. Kazin & A. A. Zhukova

Authors
  1. E. A. Guzov
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  2. V. N. Kazin
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  3. A. A. Zhukova
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Correspondence to E. A. Guzov.

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Original Russian Text © E.A. Guzov, V.N. Kazin, A.A. Zhukova, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 10, pp. 1595–1600.

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Guzov, E.A., Kazin, V.N. & Zhukova, A.A. β-Elimination in 1,1,1-Trichloro-2,2-bis(4-nitrophenyl)ethane by the Action of Sodium Nitrite in Dipolar Aprotic Solvents. Russ J Gen Chem 88, 2044–2049 (2018). https://doi.org/10.1134/S1070363218100031

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  • DOI: https://doi.org/10.1134/S1070363218100031

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