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Synthesis and Properties of Cobalt(II) Tetrakis-[4,5-di(4′-carboxy)phenylene(oxy/sulfanyl/amino)]phthalocyanines

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Abstract

Phthalonitriles with fragments of 4-hydroxy, 4-mercapto and 4-aminobenzoic acids were synthesized by nucleophilic substitution in 4-bromo-5-nitrophthalonitrile. The synthesized phthalonitriles were used to prepare octasubstituted cobalt phthalocyanines by template synthesis. The spectral properties of the products were studied.

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Correspondence to A. P. Morozova.

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Original Russian Text © A.P. Morozova, S.A. Znoiko, A.S. Vashurin, A.V. Zav’yalov, V.E. Maizlish, G.P. Shaposhnikov, 2016, published in Rossiiskii Khimicheskii Zhurnal, 2016, Vol. 60, No. 2, pp. 80–88.

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Morozova, A.P., Znoiko, S.A., Vashurin, A.S. et al. Synthesis and Properties of Cobalt(II) Tetrakis-[4,5-di(4′-carboxy)phenylene(oxy/sulfanyl/amino)]phthalocyanines. Russ J Gen Chem 88, 2020–2027 (2018). https://doi.org/10.1134/S1070363218090451

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  • DOI: https://doi.org/10.1134/S1070363218090451

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