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Synthesis of Copper-Silver Bicomponent Nanoparticles in the Presence of Nitrilotrimethylenephosphonic Acid

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Abstract

Synthesis of stable mixed nanoparticles (SMNs) by chemical co-reduction of copper and silver complexonates with sodium borohydride in an open system with the access of air oxygen was studied for the first time the. Variation of the Cu2+ to Ag+ molar ratio within 1: (0.05–0.5) enabled targeted formation of differently structured nanoparticles (core-shell type), CucoreAgshell and AgcoreCushell. It was found that, by choosing appropriate synthesis conditions, it is possible to produce oxidation-resistant copper particles protected by a shell of a precious metal or to involve the copper complex of nitrilotrimethylenephosphonic acid in silver reduction. The resulting SMNs may become widely used for obtaining various functional materials.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    E. V. Erokhina, V. N. Galashina, N. S. Dymnikova & A. P. Moryganov

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  1. E. V. Erokhina
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  2. V. N. Galashina
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  3. N. S. Dymnikova
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  4. A. P. Moryganov
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Correspondence to E. V. Erokhina.

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Original Russian Text © E.V. Erokhina, V.N. Galashina, N.S. Dymnikova, A.P. Moryganov, 2016, published in Rossiiskii Khimicheskii Zhurnal, 2016, Vol. 60, No. 2, pp. 3–10.

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Erokhina, E.V., Galashina, V.N., Dymnikova, N.S. et al. Synthesis of Copper-Silver Bicomponent Nanoparticles in the Presence of Nitrilotrimethylenephosphonic Acid. Russ J Gen Chem 88, 1951–1957 (2018). https://doi.org/10.1134/S1070363218090359

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  • DOI: https://doi.org/10.1134/S1070363218090359

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