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Stabilization of Hydroxy Tautomeric Form of Dimethyl Phosphite in the Coordination Sphere of Carbonyl Complexes of Group VI Metals

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Abstract

The interaction of dimethyl phosphite with hexacarbonyls of the chromium group metals in a nonpolar solvent has afforded metal(0) σ4,λ4-(dimethyl phosphite)pentacarbonyls containing a hydroxy tautomeric form of dimethyl phosphite in the coordination sphere. Hydrogen of the phosphite OH group in the metal(0) σ4,λ4-(dimethyl phosphite)pentacarbonyls exhibited a significant acidity, strongest for the chromium complexes. Due to the significant acidity of the phosphite hydroxyl, the metal(0) σ4,λ4-(dimethyl phosphite)-pentacarbonyls are intermediates in the electrophilic version of the Pudovik reaction.

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Authors and Affiliations

  1. Kazan Federal University, ul. Kremlevskaya 18, Kazan, 420008, Russia

    A. V. Plotnikova, A. I. Kuramshin, E. V. Kolpakova & V. I. Galkin

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  1. A. V. Plotnikova
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  2. A. I. Kuramshin
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  3. E. V. Kolpakova
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  4. V. I. Galkin
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Correspondence to A. V. Plotnikova.

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Dedicated to the 110th anniversary of M.I. Kabachnik’s birth

Original Russian Text © A.V. Plotnikova, A.I. Kuramshin, E.V. Kolpakova, V.I. Galkin, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 9, pp. 1538–1543.

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Plotnikova, A.V., Kuramshin, A.I., Kolpakova, E.V. et al. Stabilization of Hydroxy Tautomeric Form of Dimethyl Phosphite in the Coordination Sphere of Carbonyl Complexes of Group VI Metals. Russ J Gen Chem 88, 1880–1885 (2018). https://doi.org/10.1134/S1070363218090190

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  • DOI: https://doi.org/10.1134/S1070363218090190

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