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Complexing Properties of Organophosphorus Analogs of Nitrilotriacetic Acid: Aminotris(O-alkyl methylenephosphonic Acids)

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Abstract

A series of tribasic aminotris(O-alkyl methylenephosphonic acids), the closest organophosphorus analogs of nitrilotriacetic acid, a widely known complexone, were synthesized. The acid‒base properties of the synthesized acids were studied, and the stability constants of their 1: 1 complexes with two-charged cations of alkaline-earth and transition metals were determined.

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Authors and Affiliations

  1. Kazan (Volga) Federal University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    A. R. Garifzyanov, I. D. Shurygin & R. A. Cherkasov

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  1. A. R. Garifzyanov
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  2. I. D. Shurygin
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  3. R. A. Cherkasov
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Correspondence to I. D. Shurygin.

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Dedicated to the 110th anniversary of M.I. Kabachnik’s birth

Original Russian Text © A.R. Garifzyanov, I.D. Shurygin, R.A. Cherkasov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 9, pp. 1517–1523.

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Garifzyanov, A.R., Shurygin, I.D. & Cherkasov, R.A. Complexing Properties of Organophosphorus Analogs of Nitrilotriacetic Acid: Aminotris(O-alkyl methylenephosphonic Acids). Russ J Gen Chem 88, 1860–1866 (2018). https://doi.org/10.1134/S1070363218090165

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  • DOI: https://doi.org/10.1134/S1070363218090165

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