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Modification of Phosphoryl Substituents of Phthalocyanines As a Route to Targeted Tuning of Lipophilic-Hydrophilic Properties

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Abstract

О′,О′-Diethyl-[2-(3,4-dicyanophenoxy)phenyl]phosphonate has been synthesized for the first time and introduced in template condensation on lithium and zinc cations to prepare a series of new neutral and acidic phthalocyanines containing four fragments of 2-oxyphenylphosphonic acid. A scheme of modification of the peripheral substituents at the phosphoryl group was developed allowing a targeted synthesis of phthalocyanine ligands and complexes soluble in organic solvents or aqueous media.

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Authors and Affiliations

  1. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Severnyi proezd 1, Chernogolovka, 142432, Russia

    I. P. Kalashnikova & V. E. Baulin

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    D. V. Baulin, V. E. Baulin & A. Yu. Tsivadze

Authors
  1. I. P. Kalashnikova
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  2. D. V. Baulin
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  3. V. E. Baulin
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  4. A. Yu. Tsivadze
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Correspondence to I. P. Kalashnikova.

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Dedicated to the 110th anniversary of M.I. Kabachnik’s birth

Original Russian Text © I.P. Kalashnikova, D.V. Baulin, V.E. Baulin, A.Yu. Tsivadze, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 9, pp. 1510–1516.

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Kalashnikova, I.P., Baulin, D.V., Baulin, V.E. et al. Modification of Phosphoryl Substituents of Phthalocyanines As a Route to Targeted Tuning of Lipophilic-Hydrophilic Properties. Russ J Gen Chem 88, 1853–1859 (2018). https://doi.org/10.1134/S1070363218090153

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  • DOI: https://doi.org/10.1134/S1070363218090153

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