Abstract
Thermal decomposition of triethylindium has been studied under static conditions. The temperature dependence of the thermal decomposition rate is described by the equation log k = 8.1 ± 0.4–(156 600 ± 5000)/2.3 RT. The composition of gaseous thermolysis products has been determined. The obtained data suggest radical chain mechanism of the process.
References
Gribov, B.G., Domrachee, G.A., and Zhuk, B.V., Osazhdenie plenok i pokrytii razlozheniem metalloorganicheskikh soedinenii (Deposition of Films and Coatings by Decomposition of Organometallic Compounds), Moscow: Nauka, 1981.
Yudenich, S.G., Druzhkov, O.N., Mar’in, V.P., and Dodonov, V.A., Abstracts of Papers, IV Vsesoyuznoe soveshchanie “Primenenie metalloorganicheskikh soedinenii dlya polucheniya neorganicheskikh pokrytii i materialov” (IVth All-Union Meet. “Application of Organometallic Compounds for the Preparation of Inorganic Coatings and Materials”) Gor’kii, 1983, p. 42.
Larsen, C.A., Buchan, N.I., and Stringfellow, C.B., J. Crystal Growth, 1990, vol. 102, nos. 1–2, p. 103.
Stringfellow, C.B., Prog. Cryst. Growth Charact., 1989, vol. 19, p. 115.
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2016, vol. 59, no. 2, p. 30.
Squire, D.W., Ducleg, C.S., and Lin, M.C., J. Vac. Sci. Technol., B: Microelectron. Process. Phenom., 1985, vol. 3, nos. 5–6, p. 1513.
Fukuda, Y., Kobayashi, T., Yoshida, H., Sekizawa, T., and Sanada, N., Appl. Surface Sci., 2002, vol. 190, nos. 1–4, p. 279.
Sokolovskii, A.E. and Baev, A.K., Zh. Obshch. Khim., 1995, vol. 65, no. 8, p. 1270.
Sokolovskii, A.E. and Baev, A.K., Russ. J. Gen. Chem., 1993, vol. 63, no. 6, p. 845.
Sokolovskii, A.E. and Chernyak, I.N., Russ. J. Gen. Chem., 1997, vol. 67, no. 8, p. 1244.
Stepukhovich, A.D., Kinetika i mekhanizm termicheskogo krekinga alkanov (Kinetics and Mechanism of Thermal Cracking of Alkanes), Saratov: Saratov. Univ., 1965, part 1, p. 106.
Sokolovskii, A.E. and Baev, A.K., Russ. J. Gen. Chem., 1995, vol. 65, no. 5, p. 674.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.E. Sokolovskii, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1389–1391.
Rights and permissions
About this article
Cite this article
Sokolovskii, A.E. Thermal Decomposition of Triethylindium. Russ J Gen Chem 88, 1745–1747 (2018). https://doi.org/10.1134/S1070363218080297
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363218080297