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Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III)

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Abstract

The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25°C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10–5 to 1.00 × 10–3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory.

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Authors and Affiliations

  1. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    V. V. Neklyudov, G. A. Boos, G. A. Chmutova, Yu. I. Bagina & R. R. Amirov

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    M. M. Shulaeva

Authors
  1. V. V. Neklyudov
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  2. G. A. Boos
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  3. G. A. Chmutova
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  4. M. M. Shulaeva
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  5. Yu. I. Bagina
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  6. R. R. Amirov
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Correspondence to V. V. Neklyudov.

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Original Russian Text © V.V. Neklyudov, G.A. Boos, G.A. Chmutova, M.M. Shulaeva, Yu.I. Bagina, R.R. Amirov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1352–1360.

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Neklyudov, V.V., Boos, G.A., Chmutova, G.A. et al. Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III). Russ J Gen Chem 88, 1672–1680 (2018). https://doi.org/10.1134/S1070363218080194

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  • DOI: https://doi.org/10.1134/S1070363218080194

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