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Synthesis and Estimation of Radical Scavenging Activity of Tetra(meso-aryl)porphyrins Containing 2,6-Dimethoxyphenol Unit

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Abstract

Tetra(meso-aryl)porphyrins containing 2,6-dimethoxyphenol unit distant from the macrocycle and adjacent to it have been prepared. Radical scavenging activity of the obtained compounds has been estimated in the model reaction of ethylbenzene oxidation initiated by azobisisobutyronitrile. It has been shown that the phenol hydroxy group ability to inhibit ethylbenzene oxidation depends on the environment of phenol group.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, 167000, Russia

    T. K. Rocheva & D. V. Belykh

  2. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia

    L. I. Mazaletskaya & N. I. Sheludchenko

Authors
  1. T. K. Rocheva
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  2. L. I. Mazaletskaya
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  3. N. I. Sheludchenko
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  4. D. V. Belykh
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Correspondence to T. K. Rocheva.

Additional information

Original Russian Text © T.K. Rocheva, L.I. Mazaletskaya, N.I. Sheludchenko, D.V. Belykh, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1314–1319.

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Rocheva, T.K., Mazaletskaya, L.I., Sheludchenko, N.I. et al. Synthesis and Estimation of Radical Scavenging Activity of Tetra(meso-aryl)porphyrins Containing 2,6-Dimethoxyphenol Unit. Russ J Gen Chem 88, 1635–1640 (2018). https://doi.org/10.1134/S1070363218080145

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  • DOI: https://doi.org/10.1134/S1070363218080145

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