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Condensation of 1,2,4-Butanetriol with Carbonyl Compounds and Reactions of Hydroxyalkyl-1,3-dioxacyclanes

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Abstract

A mixture of isomers of 2-(1,3-dioxolan-4-yl)ethanol and 1,3-dioxan-4-ylmethanol was prepared by reaction of 1,2,4-butanetriol with paraformaldehyde. This mixture was subjected to O-alkylation, O-acylation, condensation with phenyl isocyanate, and substitution of OH groups for Cl. The relative activity of acetone derivatives of glycerol and 1,2,4-butanetriol in reactions with allyl chloride and benzyl chloride was estimated.

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, ul. Kosmonavtov 1, Ufa, Bashkortostan, 450062, Russia

    G. Z. Raskil’dina, Yu. G. Borisova & S. S. Zlotskii

Authors
  1. G. Z. Raskil’dina
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  2. Yu. G. Borisova
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  3. S. S. Zlotskii
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Correspondence to G. Z. Raskil’dina.

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Original Russian Text © G.Z. Raskil’dina, Yu.G. Borisova, S.S. Zlotskii, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1280–1284.

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Raskil’dina, G.Z., Borisova, Y.G. & Zlotskii, S.S. Condensation of 1,2,4-Butanetriol with Carbonyl Compounds and Reactions of Hydroxyalkyl-1,3-dioxacyclanes. Russ J Gen Chem 88, 1601–1605 (2018). https://doi.org/10.1134/S107036321808008X

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  • DOI: https://doi.org/10.1134/S107036321808008X

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