Abstract
Specific features of the synthesis of polycyclic crown ethers dibenzo-18-crown-6 and dibenzo-24-crown-8 and their dinitro and diamino derivatives have been studied. A mixture of isomers of dibenzocrown ether derivatives was obtained and separated. The spectral and thermal characteristics of the synthesized compounds and the kinetics of synthesis of dibenzo-24-crown-8 by the two-component condensation of pyrocatechol with 1-chloro-2-[2-(2-chloroethoxy)ethoxy]ethane in an alcoholic medium in the presence of a KOH template agent were studied.
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Original Russian Text © V.N. Glushko, N.Yu. Sadovskaya, L.I. Blokhina, M.Yu. Zhila, S.K. Belus’, E.S. Vashchenkova, I.A. Shmeleva, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1273–1279.
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Glushko, V.N., Sadovskaya, N.Y., Blokhina, L.I. et al. Synthesis of Isomeric Dinitro and Diamino Derivatives of Polycyclic Crown Ethers: Dibenzo-18-crown-6 and Dibenzo-24-crown-8. Russ J Gen Chem 88, 1595–1600 (2018). https://doi.org/10.1134/S1070363218080078
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DOI: https://doi.org/10.1134/S1070363218080078