Abstract
Using the effects of chemical polarization of nuclei, mechanism and elementary stages of photochemical reduction of 2,6-diphenyl-1,4-benzoquinone with thiols have been elucidated. The studied quinone is reduced with ethanethiol in two stages (transfer of electron followed by proton transfer). The final photolysis product is a derivative of dibenzofuran.
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Porkhun, V.I. and Rakhimov, A.I., Russ. J. Phys. Chem. (A), 2012, vol. 86, no. 11, p. 1751. doi 10.1134/SOO36024412110222
Porkhun, V.I. Rykov, S.V., and Nikiforov, G.A., Zh. Obshch. Khim., 1991, vol. 61, no. 2, p. 304.
Sviridov, B.D., Serdobov, M.V., Porkhun, V.I., and Poponova R.V., Izv. Akad. Nauk, Ser. Khim., 1983, no. 1, p. 105.
Porkhun, V.I., Aristova, Yu.V., and Sharkevich, I.V., J. Phys. Chem., 2017, no. 7, p. 1237. doi 10.1134/S003602441707024X
Mishchenko, O.G., Maslennikov, S.V., Spirina, I.V., Maslennikov, V.P., Fukin, G.K., Chesnokov, S.A., and Kurskii, Y.A., Russ. J. Gen. Chem., 2008, vol. 78, no. 11, p. 2100. doi 10.1134/S1070363207120110
Namazian, M. and Zare Namid, R., Chem. Phys. Lett., 2004, vol. 396, no. 4, p. 424. doi 10.1016/j.cplett.2004.08.089
Yun, W., Bao, Y., and Ting, W., Chin. Chem. Lett., 2003, no. 14, p. 270.
Porkhun, V.I., Aristova, Yu.V., and Porkhun, E.V., Russ. J. Phys. Chem. (A), 2017, vol. 91, no. 3, p. 472. doi 10.1134/S0036024417030220
Porkhun, V.I. and Rachimov, A.I., Russ. J. Gen. Chem., 2010, vol. 80, no. 1, p. 154. doi 10.1134/S1070363210010238
Porkhun, V.I., Aristova, Yu.V., Arshinov, A.V., Porkhun, E.V., and Sivko, A.N., Russ. J. Gen. Chem., 2017, vol. 87, no. 4, p. 703. doi 10.1134/S1070363217040077
Buchachenko, A.L., Sagdeev, R.Z., and Salikhov, K.M., Magnitnye i spinovye effekty v khimicheskih reaktsiyakh (Magnetic and Spin Effects in Chemical Reactions), Novosibirsk: Nauka, 1978, p. 296.
Barton, D. and Ollis, W.D., Comprehensive Organic Chemistry: The Syntesis and Reactions of Organic Compounds, Pergamon Press, 1979.
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Original Russian Text © V.I. Porkhun, E.V. Porkhun, D.N. Gurulev, L.V. Palatkina, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1258–1261.
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Porkhun, V.I., Porkhun, E.V., Gurulev, D.N. et al. Elementary Stages of Photochemical Reactions of Substituted 2,6-Diphenyl-para-benzoquinones with Thiols. Russ J Gen Chem 88, 1580–1583 (2018). https://doi.org/10.1134/S1070363218080042
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DOI: https://doi.org/10.1134/S1070363218080042