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Russian Journal of General Chemistry

, Volume 88, Issue 7, pp 1451–1455 | Cite as

Self-Assembly in the Systems MX2–Nicotinic Hydrazide–Pyruvic Acid (М = Со, Ni; X = Cl, CH3COO)

  • A. V. Pulya
  • I. I. Seifullina
  • L. S. Skorokhod
  • V. G. Vlasenko
  • A. L. Trigub
  • S. I. Levchenkov
Article
  • 6 Downloads

Abstract

In the course of self-assembly in the systems MX2–nicotinic hydrazide (HN)–pyruvic acid, where М = Co, Ni; X = Сl, CH3COO, complexes of composition: [CoCl(HNРv)(H2O)2], [Co(HNРv)2], [Ni(HIРv)2] have been synthesized. Local atomic structure of the coordination centers was established by the method of X-ray absorption spectroscopy. Thermal stability, electric conductivity, and magnetic susceptibility of the complexes have been determined.

Keywords

coordination compounds cobalt(II) nickel(II) nicotinic hydrazide pyruvic acid 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. V. Pulya
    • 1
  • I. I. Seifullina
    • 1
  • L. S. Skorokhod
    • 1
  • V. G. Vlasenko
    • 2
  • A. L. Trigub
    • 3
  • S. I. Levchenkov
    • 4
  1. 1.I.I. Mechnikov National UniversityOdessaUkraine
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.National Research Center “Kurchatov Institute,”MoscowRussia
  4. 4.Southern Scientific Center of the Russian Academy of SciencesRostov-on-DonRussia

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