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Synthesis and Spectral-Luminescent Properties of Zinc Sulfide Nanoparticles in a Perfluorosulfonic Membrane

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Abstract

Zinc sulfide nanoparticles were synthesized in pores of a perfluorosulfonic membrane by ion exchange fixation of Zn2+ cations followed by the processing with gaseous hydrogen sulfide. Resulting ZnS particles are X-ray amorphous, have a low density, and are clearly expressed in absorption and luminescence spectra. Features of the nanoparticles optical properties were considered in light of electrons photoexcitation on antibonding orbitals (Zn–S)*.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, nab. reki Moiki 48, St. Petersburg, 191186, Russia

    N. A. Lapatin, M. V. Puzyk & V. N. Pak

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  1. N. A. Lapatin
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  2. M. V. Puzyk
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  3. V. N. Pak
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Correspondence to V. N. Pak.

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Original Russian Text © N.A. Lapatin, M.V. Puzyk, V.N. Pak, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 6, pp. 1033–1036.

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Lapatin, N.A., Puzyk, M.V. & Pak, V.N. Synthesis and Spectral-Luminescent Properties of Zinc Sulfide Nanoparticles in a Perfluorosulfonic Membrane. Russ J Gen Chem 88, 1210–1212 (2018). https://doi.org/10.1134/S1070363218060269

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  • DOI: https://doi.org/10.1134/S1070363218060269

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