Skip to main content
SpringerLink
Log in

Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Phosphine isocyanide complexes cis-[PtCl2(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and 1H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kinzhalov, M.A. and Boyarskii, V.P., Russ. J. Gen. Chem., 2015, vol. 85, no. 10, p. 2313. doi 10.1134/S1070363215100175

    Article  CAS  Google Scholar 

  2. Mikherdov, A.S., Tyuftyakov, N.Yu., Polukeev, V.A., and Boyarskii, V.P., Russ. J. Gen. Chem., 2018, vol. 88, no. 4, p. 713. doi 10.1134/S1070363218040151

    Article  CAS  Google Scholar 

  3. Jin, M., Seki, T., and Ito, H., Chem. Commun., 2016, vol. 52, no. 52, p. 8083. doi 10.1039/C6CC03541H

    Article  CAS  Google Scholar 

  4. Ito, H., Maeda, T., and Sawamura, M., Bull. Chem. Soc. Jpn., 2007, vol. 80, no. 10, p. 1981. doi 10.1246/bcsj.80.1981

    Article  CAS  Google Scholar 

  5. Ivanov, D.M., Kinzhalov, M.A., Novikov, A.S., Ananyev, I.V., Romanova A.A., Boyarskiy, V.P., Haukka, M., and Kukushkin, V.Y., Cryst. Growth Des., 2017, no. 17, p. 1353. doi 10.1021/acs.cgd.6b01754

    Article  CAS  Google Scholar 

  6. Naik, A., Meina, L., Zabel, M., and Reiser, O., Chem. Eur. J., 2010, vol. 16, no. 5, p. 1624. doi 10.1002/chem.200901560

    Article  CAS  PubMed  Google Scholar 

  7. Mancuso, J. and Lautens, M., Org. Lett., 2003, vol. 5, no. 10, p. 1653. doi 10.1021/ol034284e

    Article  CAS  PubMed  Google Scholar 

  8. Islamova, R.M., Dobrynin, M.V., Vlasov, A.V., Eremina, A.A., Kinzhalov, M.A., Kolesnikov, I.E., Zolotarev, A.A., Masloborodova, E.A., and Luzyanin, K.V., Catal. Sci. Technol., 2017, vol. 7, no. 24, p. 5843. doi 10.1039/C7CY02013a

    Article  CAS  Google Scholar 

  9. Vicenzi, D., Sgarbossa, P., Biffis, A., Tubaro, C., Basato, M., Michelin, R.A., Lanza, A., Nestola, F., Bogialli, S., Pastore, P., and Venzo, A., Organometallics, 2013, vol. 32, no. 23, p. 7153. doi 10.1021/om400859q

    Article  CAS  Google Scholar 

  10. Gao, H. and Angelici, R.J., Organometallics, 1999, vol. 18, no. 6, p. 989. doi 10.1021/OM980829A

    Article  CAS  Google Scholar 

  11. Kinzhalov, M.A., Buldakov, A.V., Petrov, A.V., Mahmudov, K.T., Ivanov, A.Yu., and Suslonov, V.V., Russ. J. Gen. Chem., 2017, vol. 87, no. 11, p. 2605. doi 10.1134/S1070363217110159

    Article  CAS  Google Scholar 

  12. Shavaleev, N.M., Monti, F., Scopelliti, R., Baschieri, A., Sambri, L., Armaroli, N., Gratzel, M., and Nazeeruddin, M.K., Organometallics, 2013, vol. 32, no. 2, p. 460. doi 10.1021/om300894m

    Article  CAS  Google Scholar 

  13. Tsai, J.L.-L., Zou, T., Liu, J., Chen, T., Chan, A.O.-Y., Yang, C., Lok, C.-N., and Che, C.-M., Chem. Sci., 2015, vol. 6, no. 7, p. 3823. doi 10.1039/C4SC03635B

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  14. Fuertes, S., Chueca, A.J., Perálvarez, M., Borja, P., Torrell, M., Carreras, J., and Sicilia, V., ACS Appl. Mater. Interfaces, 2016, vol. 8, no. 25, p. 16160. doi 10.1021/acsami.6b03288

    Article  CAS  PubMed  Google Scholar 

  15. Boyarskiy, V.P., Bokach, N.A., Luzyanin, K.V., and Kukushkin, V.Y., Chem. Rev., 2015, vol. 115, p. 2698. doi 10.1021/cr500380d

    Article  CAS  PubMed  Google Scholar 

  16. Kinzhalov, M.A., Novikov, A.S., Luzyanin, K.V., Haukka, M., Pombeiro, A.J.L., and Kukushkin, V.Y., New J. Chem., 2016, vol. 40, no. 1, p. 521. doi 10.1039/C5NJ02564H

    Article  CAS  Google Scholar 

  17. Anisimova, T.B., Kinzhalov, M.A., Kuznetsov, M.L., Guedes da Silva, M.F.C., Zolotarev, A.A., Kukushkin, V.Y., Pombeiro, A.J.L., and Luzyanin, K.V., Organometallics, 2016, vol. 35, no. 20, p. 3569. doi 10.1021/acs.organomet.6b00635

    Article  CAS  Google Scholar 

  18. Bertani, R., Mozzon, M., Michelin, R.A., Benetollo, F., Bombieri, G., Castilho, T.J., and Pombeiro, A.J.L., Inorg. Chim. Acta, 1991, vol. 189, no. 2, p. 175. doi 10.1016/s0020-1693(00)80186-3

    Article  CAS  Google Scholar 

  19. Hashmi, A.S.K., Lothschutz, C., Bohling, C., Hengst, T., Hubbert, C., and Rominger, F., Adv. Synth. Catal., 2010, vol. 352, no. 17, p. 3001. doi 10.1002/adsc.201000472

    Article  CAS  Google Scholar 

  20. Hubbert, C., Breunig, M., Carroll, K.J., Rominger, F., and Hashmi, A.S.K., Austral. J. Chem., 2014, vol. 67, no. 3, p. 469. doi 10.1071/ch13546

    Article  CAS  Google Scholar 

  21. Chay, R.S., Luzyanin, K.V., Kukushkin, V.Y., Guedes da Silva, M.F.C., and Pombeiro, A.J.L., Organometallics, 2012, vol. 31, p. 2379. doi 10.1021/om300020j

    Article  CAS  Google Scholar 

  22. Boyarskiy, V.P., Luzyanin, K.V., and Kukushkin, V.Y., Coord. Chem. Rev., 2012, vol. 256, p. 2029. doi 10.1016/j.ccr.2012.04.022

    Article  CAS  Google Scholar 

  23. Slaughter, L.M., ACS Catal., 2012, vol. 2, p. 1802. doi 10.1021/cs300300y

    Article  CAS  Google Scholar 

  24. Luzyanin, K.V., Pombeiro, A.J.L., Haukka, M., and Kukushkin, V.Y., Organometallics, 2008, vol. 27, no. 20, p. 5379. doi 10.1021/om800517c

    Article  CAS  Google Scholar 

  25. Chay, R.S., Rocha, B.G.M., Pombeiro, A.J.L., Kukushkin, V.Y., and Luzyanin, K.V., ACS Omega, 2018, vol. 3, no. 1, p. 863. doi 10.1021/acsomega.7b01688

    Article  CAS  Google Scholar 

  26. Rocha, B.G.M., Valishina, E.A., Chay, R.S., da Silva, M., Buslaeva, T.M., Pombeiro, A.J.L., Kukushkin, V.Y., and Luzyanin, K.V., J. Catal., 2014, vol. 309, p. 79. doi 10.1016/j.jcat.2013.09.003

    Article  CAS  Google Scholar 

  27. Chatt, J., Richards, R.H., and Royston, G.H.D, Inorg. Chim. Acta, 1972, vol. 6, no. 4, p.669.

    Article  CAS  Google Scholar 

  28. Miss, E.M.B., Chatt, J., and Richards, R.L., J. Chem. Soc. A, 1971, p. 21. doi 10.1039/J19710000021

    Google Scholar 

  29. Michelin, R.A., Facchin, G., and Uguagliati, P., Inorg. Chem., 1984, vol. 23, no. 7, p. 961. doi 10.1021/ic00175a033

    Article  CAS  Google Scholar 

  30. Manojlovicmuir, L., Muir, K.W., and Solomun, T., J. Organomet. Chem., 1977, vol. 142, no. 2, p. 265. doi 10.1016/s0022-328x(00)94349-3

    Article  CAS  Google Scholar 

  31. Crociani, B. and Richards, R.L., J. Organomet. Chem., 1978, vol. 144, no. 1, p. 85. doi 10.1016/s0022-328x (00)98093-8

    Article  CAS  Google Scholar 

  32. Briggs, J.R., Crocker, C., and Shaw, B.L., Inorg. Chim. Acta, 1981, vol. 51, no. 1, p. 15. doi 10.1016/s0020-1693(00)88309-7

    Article  CAS  Google Scholar 

  33. Knorr, M., Jourdain, I., Crini, G., Frank, K., Sachdev, H., and Strohmann, C., Eur. J. Inorg. Chem., 2002, no. 9, p. 2419. doi 10.1002/1099-0682(200209) 2002:9<2419::AID-EJIC2419>3.0.CO;2-U

    Article  Google Scholar 

  34. Yakimanskiy, A., Boyarskaya, I., and Boyarskiy, V., J. Coord. Chem., 2013, vol. 66, no. 20, p. 3592. doi 10.1080/00958972.2013.847185

    Article  CAS  Google Scholar 

  35. Kinzhalov, M.A., Zolotarev, A.A., and Boyarskiy, V.P., J. Struct. Chem., 2016, vol. 57, no. 4, p. 822. doi 10.1134/s0022476616040302.

    Article  CAS  Google Scholar 

  36. Kinzhalov, M.A., Luzyanin, K.V., Boyarskaya, I.A., Starova, G.L., and Boyarskiy, V.P., J. Mol. Struct., 2014, vol. 1068, p. 222. doi 10.1016/j.molstruc.2014.04.025

    Article  CAS  Google Scholar 

  37. Martinez-Martinez, A.J., Chicote, M.T., and Bautista, D., Inorg. Chim. Acta, 2012, vol. 382, p. 203. doi 10.1016/j.ica.2011.11.038

    Article  CAS  Google Scholar 

  38. Anisimova, T.B., Kinzhalov, M.A., Guedes da Silva, M.F.C., Novikov, A.S., Kukushkin, V.Y., Pombeiro, A.J.L., and Luzyanin, K.V., New J. Chem., 2017, vol. 41, no. 9, p. 3246. doi 10.1039/C7NJ00529F

    Article  CAS  Google Scholar 

  39. Sluch I.M., Miranda A.J., and Slaughter L.M., Cryst. Growth Des., 2009, vol. 9, no. 3, p. 1267. doi 10.1021/cg801116q

    Article  CAS  Google Scholar 

  40. Michelin, R.A., Zanotto, L., Braga, D., Sabatino, P., and Angelici, R.J., Inorg. Chem., 1988, vol. 27, no. 1, p. 85. doi 10.1021/ic00274a019

    Article  CAS  Google Scholar 

  41. Johansson, M.H. and Otto, S., Acta Crystallogr., Sect. C, 2000, vol. 56, p. e12. doi 10.1107/S0108270199012147

    Article  Google Scholar 

  42. Klingenberg, M.A., Bogachenkov, A.S., Kinzhalov, M.A., Vasilyev, A.V., and Boyarskiy, V.P., New J. Chem., 2016, vol. 40, no. 4, p. 3336. doi 10.1039/c5nj03038b

    Article  CAS  Google Scholar 

  43. Luzyanin, K.V., Pombeiro, A.J.L., Haukka, M., and Kukushkin, V.Y., Organometallics, 2008, vol. 27, p. 5379. doi 10.1021/om800517c

    Article  CAS  Google Scholar 

  44. Tskhovrebov, A.G., Luzyanin, K.V., Haukka, M., and Kukushkin, V.Y., J. Chem. Crystallogr., 2012, vol. 42, no. 12, p. 1170. doi 10.1007/s10870-012-0371-0

    Article  CAS  Google Scholar 

  45. Palatinus, L. and Chapuis, G., J. Appl. Crystallogr., 2007, vol. 40, p. 786. doi 10.1107/s0021889807029238

    Article  CAS  Google Scholar 

  46. Palatinus, L. and van der Lee A., J. Appl. Crystallogr., 2008, vol. 41, p. 975. doi 10.1107/s0021889808028185

    Article  CAS  Google Scholar 

  47. Sheldrick, G.M., Acta Crystallogr., 2015, vol. 71, p. 3. doi 10.1107/s2053273314026370

    Google Scholar 

  48. Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008, vol. 64, p. 112. doi 10.1107/S0108767307043930

    Article  CAS  Google Scholar 

  49. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystallogr., 2009, vol. 42, p. 339. doi 10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  50. Spek, A.L., Acta Crystallogr., Sect. C, 2015, vol. 71, p. 9. doi 10.1107/s2053229614024929

    Article  CAS  Google Scholar 

  51. CrysAlisPro. A.T., Version 1.171.36.20 (release 27-06-2012).

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    M. A. Kinzhalov, M. V. Kashina, A. S. Mikherdov, S. A. Katkova & V. V. Suslonov

Authors
  1. M. A. Kinzhalov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. V. Kashina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Mikherdov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. A. Katkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Suslonov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. A. Kinzhalov.

Additional information

Original Russian Text © M.A. Kinzhalov, M.V. Kashina, A.S. Mikherdov, S.A. Katkova, V.V. Suslonov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 6, pp. 1000–1007.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kinzhalov, M.A., Kashina, M.V., Mikherdov, A.S. et al. Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions. Russ J Gen Chem 88, 1180–1187 (2018). https://doi.org/10.1134/S107036321806021X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107036321806021X

Keywords

Search

Navigation