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Analysis of Hydrogen Bonding Network in the Systems Containing Chloride-Based Ionic Liquids with Cellulose/Cellobiose by Fourier-Transform Infrared Spectroscopy

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Abstract

Hydrogen bonds formed upon dissolution of cellulose and cellobiose in ionic liquids, 1-butyl-3- methylpyridinium and 1-butyl-3-methylimidazolium chlorides, have been analyzed and characterized by means of Fourier-transform infrared spectroscopy and quantum-chemical calculation. The obtained data have been used for assignment of absorption bands of individual OH groups and determination of hydrogen bonds energy in the solutions.

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Authors and Affiliations

  1. St. Petersburg State University of Industrial Technologies and Design, ul. Bol’shaya Morskaya 18, St. Petersburg, 191186, Russia

    D. A. Kashirskii, E. S. Sashina, T. V. Artamonova & L. V. Myznikov

Authors
  1. D. A. Kashirskii
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  2. E. S. Sashina
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  3. T. V. Artamonova
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  4. L. V. Myznikov
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Corresponding author

Correspondence to E. S. Sashina.

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Original Russian Text © D.A. Kashirskii, E.S. Sashina, T.V. Artamonova, L.V. Myznikov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 5, pp. 792–799.

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Kashirskii, D.A., Sashina, E.S., Artamonova, T.V. et al. Analysis of Hydrogen Bonding Network in the Systems Containing Chloride-Based Ionic Liquids with Cellulose/Cellobiose by Fourier-Transform Infrared Spectroscopy. Russ J Gen Chem 88, 935–942 (2018). https://doi.org/10.1134/S107036321805016X

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  • DOI: https://doi.org/10.1134/S107036321805016X

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