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Functionalized Polynorbornenes with Oligoether Units and Luminophoric Iridium(III) Complexes in Side Chains. Synthesis, Photophysical, and Biological Properties

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Abstract

Copolymers with oligoether units and luminophoric iridium(III) complexes in the side chains have been synthesized via metathesis polymerization. The copolymers containing different luminophoric iridium(III) complexes have exhibited strong green, blue-green, or red photoluminescence. The copolymers are soluble in water, forming micelles with average size 14‒20 nm. The copolymer with red photoluminescence has low cytotoxicity with respect to epidermoid human carcinoma cells (line A431).

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Acknowledgments

This study was financially supported by the Russian Foundation for Basic Research (project nos. 15-43-02178-r_povolzh’e_a, 16-33-0234-mol_a, 16-34-60117-mol_a_dk).

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Authors and Affiliations

  1. G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603950, Russia

    E. O. Platonova, A. V. Rozhkov, S. A. Lermontova, L. G. Klapshina, A. N. Konev, L. N. Bochkarev & G. A. Abakumov

Authors
  1. E. O. Platonova
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  2. A. V. Rozhkov
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  3. S. A. Lermontova
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  4. L. G. Klapshina
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  5. A. N. Konev
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  6. L. N. Bochkarev
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  7. G. A. Abakumov
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Corresponding author

Correspondence to L. N. Bochkarev.

Additional information

Original Russian Text © E.O. Platonova, A.V. Rozhkov, S.A. Lermontova, L.G. Klapshina, A.N. Konev, L.N. Bochkarev, G.A. Abakumov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 4, pp. 650–654.

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Platonova, E.O., Rozhkov, A.V., Lermontova, S.A. et al. Functionalized Polynorbornenes with Oligoether Units and Luminophoric Iridium(III) Complexes in Side Chains. Synthesis, Photophysical, and Biological Properties. Russ J Gen Chem 88, 731–735 (2018). https://doi.org/10.1134/S1070363218040175

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  • DOI: https://doi.org/10.1134/S1070363218040175

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