Russian Journal of General Chemistry

, Volume 88, Issue 4, pp 705–712 | Cite as

Synthesis and Isomer Composition of 2-Polyfluoroalkoxy-1,3,2-dioxaphospholanes and -phosphinanes

  • N. K. Gusarova
  • S. I. Verkhoturova
  • S. N. Arbuzova
  • T. I. Kazantseva
  • A. I. Albanov
  • A. M. Nalibaeva
  • G. K. Bishimbaeva
  • K. A. Apartsin
  • V. V. Kireeva
  • B. A. Trofimov
Article
  • 6 Downloads

Abstract

Polyfluoroalkanols readily reacted with 2-chloro-1,3,2-dioxaphospholanes and 2-chloro-1,3,2-dioxaphosphinanes in hexane in the presence of triethylamine (–10 to 25°C, 5 h) to give 2-polyfluoroalkoxy-1,3,2- dioxaphospholanes and 2-polyfluoroalkoxy-1,3,2-dioxaphosphinanes in 48–72% yield. The products were found to exist as mixtures of cis and trans isomers with the trans isomer predominating for the phospholanes and cis isomer predominating for the phosphinanes according to the 1H, 13C, 19F, and 31P NMR data.

Keywords

2-chloro-1,3,2-dioxaphospholanes 2-chloro-1,3,2-dioxaphosphinanes polyfluoroalkanols 2-polyfluoroalkoxy-1,3,2-dioxaphospholanes 2-polyfluoroalkoxy-1,3,2-dioxaphosphinanes 

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Notes

Acknowledgments

This study was performed under financial support by the President of the Russian Federation (program for support of leading scientific schools, project no. NSh-7145.2016.3) using the facilities of the Baikal Joint Analytical Center, Siberian Branch, Russian Academy of Sciences.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • N. K. Gusarova
    • 1
  • S. I. Verkhoturova
    • 1
  • S. N. Arbuzova
    • 1
  • T. I. Kazantseva
    • 1
  • A. I. Albanov
    • 1
  • A. M. Nalibaeva
    • 2
  • G. K. Bishimbaeva
    • 2
  • K. A. Apartsin
    • 3
  • V. V. Kireeva
    • 3
  • B. A. Trofimov
    • 1
  1. 1.Favorskii Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia
  2. 2.Sokol’skii Institute of FuelCatalysis, and ElectrochemistryAlmatyKazakhstan
  3. 3.Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian BranchRussian Academy of SciencesIrkutskRussia

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