Russian Journal of General Chemistry

, Volume 88, Issue 3, pp 605–606 | Cite as

Formation of the P–C and C–C bonds in the Reaction of 2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one with Dimethyl Acetylenedicarboxylate under Mild Conditions

  • V. F. Mironov
  • G. A. Ivkova
  • R. Z. Musin
  • L. M. Abdrakhmanova
Letters to the Editor


2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one reacts under mild conditions with dimethyl acetylenedicarboxylate with the participation by only threecoordinated phosphorus atom and the formation of 2-(5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-3,4-dimethoxycarbonylbenzo[f]-1,2-oxaphosphepine-2,5-dione. During the process, simultaneous formation of the P–C and C–C bonds takes place.


diazaphosphol dioxaphosphorine dimethyl acetylenedicarboxylate benzooxaphosphepine 


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. F. Mironov
    • 1
    • 2
  • G. A. Ivkova
    • 2
  • R. Z. Musin
    • 1
  • L. M. Abdrakhmanova
    • 1
  1. 1.Arbuzov Institute of Organic and Physical ChemistryKazan Scientific Center of the Russian Academy of SciencesKazan, TatarstanRussia
  2. 2.Kazan (Volga Region) Federal UniversityKazan, TatarstanRussia

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