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Synthesis and Special Features of Electrochemical Behavior of Tungsten Oxide Deposited on Various Substrates

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Abstract

Tungsten oxides were electrochemically deposited from a metastable acidic solution of isopolytungstate on simple glassy carbon electrodes and glassy carbon electrodes coated with a film of a conductive polymer poly(3,4-ethylenedioxythiophene). It was found by the cyclic voltammetry method that the redox capacity of tungsten oxide deposits on the conductive polymer film is noticeably greater than on glassy carbon, which indirectly points to its high dispersion. The morphology of the tungsten oxide deposits was studied using scanning electron microscopy. The tungsten valence state in the composition of surface tungsten oxides was determined by the X-ray electron spectroscopy method.

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References

  1. Masahiro, S. and Eberhard, S., Chem. Rev., 1998, vol. 98, p. 219. doi 10.1021/cr9603946

    Article  Google Scholar 

  2. Ammam, M., J. Mater. Chem. (A), 2013, vol. 1, p. 6291. doi 10.1039/C3TA01663C

    Article  CAS  Google Scholar 

  3. Keita, B., Nadjo, L., and Haeussler, J.P., Electroanal. Chem., 1988, vol. 243, p. 481. doi 10.1016/0022-0728 (88)80051-2

    Article  CAS  Google Scholar 

  4. Tsze, V., Borzenko, M.I., Tsyirlina, G.A., and Petrii, O.A., Elektrokhim., 2002, vol. 38, no. 11, p. 1250.

    Google Scholar 

  5. Granqvist, C.G., Sol. Energy Mater. Sol. Cells, 2000, vol. 60, p. 201. doi 10.1016/S0927-0248(99)00088-4

    Article  CAS  Google Scholar 

  6. Monk, P.M.S., Mortimer, R.J., and Rosseinsky, D.R., Electrochromism: Fundamentals and Applications, Weinheim: Wiley-VCH Verlag GmbH, 2007, p. 80.

    Google Scholar 

  7. Jensen, J., Hosel, M., Dyer, A.L., and Krebs, F.C., Adv. Funct. Mater., 2015, vol. 25, p. 2073. doi/adfm.201403765

    Article  CAS  Google Scholar 

  8. Matsui, J., Kikuchi, R., and Miyashita, T., J. Am. Chem. Soc., 2014, vol. 136, p. 842. doi 10.1021/ja4107786

    Article  CAS  Google Scholar 

  9. Thakur, V.K., Ding, G., Ma, J., Lee, P.S., and Lu, X., Adv. Mater., 2012, vol. 24, p. 4071. doi adma.201200213

    Article  CAS  Google Scholar 

  10. Granqvist, C.G., Sol. Energy Mater. Sol. Cells, 2012, vol. 99, p. 1. doi 10.1016/j.solmat.2011.08.021.K

    Article  CAS  Google Scholar 

  11. Kumagai, N., Kumagai, N., and Tanno, K., Electrochim. Acta, 1987, vol. 32, p. 1521. doi 10.1016/0013-4686(87) 85096-X

    Article  CAS  Google Scholar 

  12. Kumagai, N., Matsuura, Y., Kumagai, N., and Tanno, K., J. Electrochem. Soc., 1992, vol. 139, p. 3553. doi 10.1149/1.2069120

    Article  CAS  Google Scholar 

  13. Kumagai, N. and Yashiro, H., Solid State Ionics, 1997, vol. 98, p. 159. doi 10.1016/S0167-2738(97)00114-8

    Article  CAS  Google Scholar 

  14. Wang, Y.-H., Wang, C.-C., Cheng, W.-Y., and Lu, S.-Y., Carbon, 2014, vol. 69, p. 287. doi 10.1016/j.carbon.2013.12.027

    Article  CAS  Google Scholar 

  15. Gao, l., Wang, X., Xie, Z, Song, W., Wang, L., Wu, X., Qu, F., Chen, D., and Shen, G., J. Mater. Chem. (A), 2013, vol. 1, no. 24, p. 7167. doi 10.1039/C3TA10831G

    Article  CAS  Google Scholar 

  16. Dautremont-Smith, W.C., Green, M, and Kang, K.S., Electrochim. Acta, 1977, vol. 22, p. 751. doi 10.1016/0013-4686(77)80031-5

    Article  CAS  Google Scholar 

  17. Reichman, B. and Bard, A.J., J. Electrochem. Soc., 1979, vol. 126, p. 583. doi 10.1149/1.2129091

    Article  CAS  Google Scholar 

  18. Davazoglou, D., Leveque, G., and Donnadieu, A., Solar Energy Mater., 1988, vol. 17, p. 379. doi 10.1016/0165-1633(88)90020-2

    Article  CAS  Google Scholar 

  19. Gesheva, K., Szekeres, A., and Ivanova, T., Sol. Energy Mater. Sol. Cells, 2003, vol. 76, p. 563. doi 10.1016/S0927-0248(02)00267-2

    Article  CAS  Google Scholar 

  20. Yu, Zh., Jia, X., Du, J., and Zhang, J., Sol. Energy Mater. Sol. Cells, 2000, vol. 64, p. 55. doi 10.1016/S0927-0248(0000)00043-X

    Article  CAS  Google Scholar 

  21. Yamanaka, K., Japan J. Appl. Phys., 1981, vol. 20, p. L307. doi 10.1143/JJAP.20.L307

    Google Scholar 

  22. Lvovich, V. and Scheeline, A., Computer. Chem., 1997, vol. 69, p. 454. doi 10.1021/ac9606261

    CAS  Google Scholar 

  23. Tiwari, A. and Gong, S.Q., Electroanalysis, 2008, vol. 20, p. 1775. doi elan.200804237

    Article  CAS  Google Scholar 

  24. Qu, H., Zhang, X., Zhang, H., Tian, Y., Lia, N., Li, H., Hou, S., Li, X., Zhao, J., and Li, Y. Sol. Energy Mater. Sol. Cells, 2017, vol. 163, p. 23. doi 10.1016/j.solmat.2016.12.030

    Article  CAS  Google Scholar 

  25. Granqvist, C.G., Handbook of Inorganic Electrochromic Materials, Amsterdam: Elsevier, 1995. p. 87.

    Google Scholar 

  26. Timofeeva, E.V., Tsirlina, G.A., and Petrii, O.A., Russ. J. Electrochem., 2003, vol. 39, no. 7, p. 716. doi 10.1023/A:1024869801164

    Article  CAS  Google Scholar 

  27. Pop, M.S., Geteropoli-i Izopolioksometallaty (Heteropoly-and Isopolyoxometalates), Novosibirsk: Nauka, 1990, p. 139.

    Google Scholar 

  28. Kabanov, V. and Spitsyn, V.I., Zh. Obshch. Khim., 1964, vol. 9, p. 1844.

    CAS  Google Scholar 

  29. Kazanskii, L.P., Fedotov, M.A., and Spitsyn V.i., Dokl. Akad. Nauk SSSR, 1977, vol. 234, p. 1376.

    CAS  Google Scholar 

  30. Cruywagen, J.J., Adv. Inorg. Chem., 2000, vol. 49, p. 127. doi 10.1016/S0898-8838(08)60270-6

    Article  CAS  Google Scholar 

  31. Tytko, K.H. and Glemser, O., Adv. Inorg. Chem. Radiochem., 1976, vol. 19, p. 239. doi 10.1016/S0065-2792(08)60073-4

    Article  CAS  Google Scholar 

  32. Hastings, J.J. and Howarth, W., J. Chem. Soc. Dalton Trans., 1992, p. 209. doi 10.1039/DT9920000209

    Google Scholar 

  33. Himeno, S. and Kitazumi, I., Inorg. Chim. Acta, 2003, vol. 355, p. 81. doi 10.1016/S0020-1693(03)00313-X

    Article  CAS  Google Scholar 

  34. Redkin, A.F. and Bondarenko, G.V., J. Solution. Chem., 2010, vol. 39, p. 1549. doi 10.1007/s10953-010-9595-9

    Article  CAS  Google Scholar 

  35. Picquart, M., Castro-Garcia, S., Livage, J., Julien, C., and Haro-Poniatowski, E., J. Sol-Gel Sci. Tech., 2000, vol. 18, p.,199. doi 10.1023/A: 1008775318802

    Google Scholar 

  36. Pugolovkin, L.V., Vassil’ev, S.Yu., Borzenko, M.I., Laurinavichyute, V.K., and Tsirlina, G.A., Russ. Chem. Bull., 2013, vol. 62, no. 6, p. 1317. doi 10.1007/s11172-013-0185-z

    Article  CAS  Google Scholar 

  37. Tourillon, G., Polythiophene and Its Derivatives. Handbook of Conducting Polymers, New York: Marcel Dekker, 1986, p. 293.

    Google Scholar 

  38. Kondratiev, V.V., Pogulaichenko, N.A., Tolstopjatova, E.G., and Malev, V.V., J. Solid State Electrochem., 2011 vol. 15, nos. 11–12, p. 2383. doi 10.1007/s10008-011-1494-5

    Article  CAS  Google Scholar 

  39. Plyasova, L.M., Molina, I.Y., Kustova, G.N., Rudina, N.A., Borzenko, M.I., Tsirlina, G.A., and Petrii, O.A., J. Solid State Electrochem., 2005, vol. 9, p. 371. doi 10.1007/s10008-004-0642-6

    Article  CAS  Google Scholar 

  40. Tolstopjatova, E.G., Eliseeva, S.N., Poguljaichenko, N.A., and Kondrat’ev, V.V., Vestn. SPb. Gos. Univ., Ser. 4, 2007, vol. 3, p. 100.

    Google Scholar 

  41. Aoki K., Mukoyama, I., and Chen, J., Russ. J. Electrochem., 2004, vol. 40, no. 3, p. 280. doi 10.1023/B:RUEL.0000019665.59805.4c

    Article  CAS  Google Scholar 

  42. Mukoyama, I., Aoki, K., and Chen, J., J. Electroanal. Chem., 2002, vol. 531, p. 133. doi 10.1016/S0022-0728 (02)01063-X

    Article  CAS  Google Scholar 

  43. Alpatov, N.M., and Ovsyannikova, E.V., Ross. Khim. Zh., 2005, vol. 49. p. 93.

    Google Scholar 

  44. Bobacka, J, Ivaska, A., and Grzeszczuk, M., Synth. Meth., 1991, vol. 44, p. 9. doi 10.1016/0379-6779(91) 91853-3

    Article  CAS  Google Scholar 

  45. Leftheriotis, G., Papaefthimiou, S., Yianoulis, P., Siokou, A., and Kefalas, D., Appl. Surf. Sci., 2003, vol. 218, p. 276. doi 10.1016/S0169-4332(03)00616–0

    Article  Google Scholar 

  46. McGuire, G.E., Schweitzer G.K., and Carlson, A.T., Inorg. Chem., 1973, vol. 12, p. 2450. doi 10.1021/ic50128a045

    Article  CAS  Google Scholar 

  47. Siokou, A., Leftheriotis, G., Papaefthimiou, S., and Yianoulis, P., Surf. Sci., 2001, vols. 482–485, p. 294. doi 10.1016/S0039-6028(01)00714-2

    Article  Google Scholar 

  48. Leftheriotis, G., Papaefthimiou S., Yiannoulis, P., and Siokou, A., Thin Solid Films, 2001, vol. 384, p. 298. doi 10.1016/S0040-6090(0000)01828-9

    Article  CAS  Google Scholar 

  49. Clatot, J., Campet, G., Zeinert, A., Labrugere, C., Nistor, M., and Rougier, A., Sol. Energy Mater. Sol. Cells, 2011 vol. 95, p. 2357. doi 10.1016/j.solmat.2011.04.006

    Article  CAS  Google Scholar 

  50. Wong, H.Y., Ong, C.W., Kwok, R.W., Wong, K.W., Wong, S.P., and Cheung, W.Y., Thin Solid Films, 2000, vol. 376, p. 131. doi 10.1016/S0040-6090(0000)01204-9

    Article  CAS  Google Scholar 

  51. Azimirad, R., Naseri, N., Akhavan, O., and Moshfegh, A.Z., J. Phys. (D), 2007, vol. 40, p. 1134. doi 10.1088/0022-3727/40/4/034

    CAS  Google Scholar 

  52. Lin, Y.-S., Chiang, Y.-L., and Lai, J.-Y., Solid State Ionics, 2009 vol. 180, p. 99. doi 10.1016/j.ssi.2008.10.009

    Article  CAS  Google Scholar 

  53. Bertus, L.M., Faure, C., Danine, A., Labrugere, C., Campet, G., Rougier, A., and Duta, A., Mater. Shem. Physics, 2013, vol. 140, p. 49. doi 10.1016/j.matchemphys.2013.02.047

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Volta” Scientific and Technical Firm, nab. Obvodnogo kanala 150, St. Petersburg, 192020, Russia

    D. V. Zhuzhel’skii, K. D. Yalda & V. N. Spiridonov

  2. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    R. V. Apraksin & V. V. Kondrat’ev

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  1. D. V. Zhuzhel’skii
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  2. K. D. Yalda
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  4. R. V. Apraksin
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  5. V. V. Kondrat’ev
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Correspondence to D. V. Zhuzhel’skii.

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Original Russian Text © D.V. Zhuzhel’skii, K.D. Yalda, V.N. Spiridonov, R.V. Apraksin, V.V. Kondrat’ev, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 3, pp. 493–501.

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Zhuzhel’skii, D.V., Yalda, K.D., Spiridonov, V.N. et al. Synthesis and Special Features of Electrochemical Behavior of Tungsten Oxide Deposited on Various Substrates. Russ J Gen Chem 88, 520–527 (2018). https://doi.org/10.1134/S1070363218030209

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  • DOI: https://doi.org/10.1134/S1070363218030209

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