Russian Journal of General Chemistry

, Volume 88, Issue 3, pp 505–508 | Cite as

Six-Nuclear Complexes of Platinum(II) and Palladium(II) with Mercamine and β-Mercaptoethanol

  • A. N. Azizova
  • D. B. Tagiev
  • Sh. G. Kasumov
  • Kh. I. Gasanov


The platinum(II) and palladium(II) complexes [Pt6(SCH2CH2NH2)8]Cl4 and [Pd6(SCH2CH2OH)8 Cl4· 5H2O with mercamine and β-mercaptoethanol, respectively, were synthesized. It was found on the basis of the comparison of IR and X-ray electron spectra of the ligands and complexes, and also of the data of X-ray diffraction analysis that the bidentate coordination of ligands through sulfur and nitrogen atoms is realized in the platinum(II) complex. In the palladium(II) complex β-mercaptoethanol is coordinated in a mixed-mode type. In both complexes sulfur atoms of the ligands occupy a bridging position.


mercamine platinum and palladium complexes chelating six-nuclear type of coordination mixed coordination 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Gasanov, Kh.I., Fatullaeva, S.S., Tagiev, D.B., and Mirzai, J.I., Azerb. Khim. Zh., 1998, no. 3, p. 38.Google Scholar
  2. 2.
    Gasanov, Kh.I., Zh. Khim. Khim. Tekhnol., 2000, vol. 43, no. 33, p. 133.Google Scholar
  3. 3.
    Bellamy, L.J., The Infra-Red Spectra of Complex Molecules, New York: John Wiley, 1957.Google Scholar
  4. 4.
    Zheligovskaya, N.N., Kasymbekov, D.Kh., Butinchieva, T.S., and Osmanov, Kh.K., Koord. Khim., 1992, vol. 18, no. 32, p. 176.Google Scholar
  5. 5.
    Jocelyn, P.C., Biochemistry of the SH Group, New York: Academic Press, 1972.Google Scholar
  6. 6.
    Kokozei, V.N., Polyakov, V.R., Simonov, Yu.A., and Senkevich, A.V., Zh. Neorg. Khim., 1992, vol. 37, no. 8, p. 1810.Google Scholar
  7. 7.
    Shebaldova, A.D. and Safronova, D.A., Koord. Khim., 1995, vol. 21, no. 6, p. 486.Google Scholar
  8. 8.
    Chandresekharan, M., Udupa, M.R., and Aravamudan, G., J. Inorg. Nucl. Chem., 1974, vol. 36, no. 5, p. 1153.CrossRefGoogle Scholar
  9. 9.
    Efimenko, I.A., Gasanov, Kh.I., Ivanova, N.A., Lokshin, B.V., Zakharov, A.A., and Kuz’mina, L.G., Russ. J. Coord. Chem., 2000, vol. 26, no. 2, p. 112.Google Scholar
  10. 10.
    Bol’shakova, L.D. and Lyapkin, V.V., Russ. J. Inorg. Chem., 1998, vol. 43, no. 1, p. 69.Google Scholar
  11. 11.
    Braun, D.W., Floyd, A.J., and Sainsbury, M., Organic Spectroscopy, New York: John Wiley, 1988.Google Scholar
  12. 12.
    Azizova, A.N.,, K.G., Asgerov, R.K., Kapilovich, M.N., Zen, Ma, and Pompeyro, A.J.L., Inorg. Chem. Commun., 2013, vol. 29, p. 37. doi 10.1016/j.inoche.2012.12.012CrossRefGoogle Scholar
  13. 13.
    Kukushkin, V.Yu., Tkachuk, V.M., Krol’, I.A., Starikova, Z.A., Zhdanov, B.V., and Kiseleva, N.P., Zh. Obshch. Khim., 1991, vol. 61, no. 1, p. 51.Google Scholar
  14. 14.
    Nepol, J.R. and Dubey, S.N., J. Indian Chem. Soc., 1988, vol. 65, no. 11, p. 795.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. N. Azizova
    • 1
  • D. B. Tagiev
    • 1
  • Sh. G. Kasumov
    • 2
  • Kh. I. Gasanov
    • 2
  1. 1.Academician M. Nagiev Institute of Catalysis and Inorganic ChemistryNational Academy of Sciences of AzerbaijanBakuAzerbaijan
  2. 2.Azerbaijan Medical UniversityBakuAzerbaijan

Personalised recommendations