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Synthesis and Structure of a Copper(II) Complex of N,N'-Bis(di-para-tolylphosphinoylmethyl)-1,8-diamino- 3,6-dioxaoctane

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Abstract

A copper(II) complex of N,N'-bis(di-para-tolylphosphinoylmethyl)-1,8-diamino-3,6-dioxaoctane was synthesized and its crystal structure was established. The inner coordination sphere of the complex is a strongly distorted trigonal bipyramid. Coordination involves the phosphoryl oxygen atoms, nitrogen atoms, and ether oxygen atom, and one axial position is occupied by a water molecule.

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Correspondence to N. V. Davletshina.

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Original Russian Text © A.R. Garifzyanov, N.V. Davletshina, A.Z. Gaynullin, K.A. Ivshin, O.N. Kataeva, R.A. Cherkasov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 1, pp. 162–165.

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Garifzyanov, A.R., Davletshina, N.V., Gaynullin, A.Z. et al. Synthesis and Structure of a Copper(II) Complex of N,N'-Bis(di-para-tolylphosphinoylmethyl)-1,8-diamino- 3,6-dioxaoctane. Russ J Gen Chem 88, 154–157 (2018). https://doi.org/10.1134/S1070363218010280

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  • DOI: https://doi.org/10.1134/S1070363218010280

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