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Reaction of 1,4-benzoquinones with PH-phosphonium salts

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Abstract

A novel approach has been proposed to the synthesis of phosphonium salts containing a 1,4-dihydroxybenzo fragment via reaction of 2-methyl-1,4-benzoquinone or 2-isopropyl-5-methyl-1,4-benzoquinone with PH-phosphonium salts generated in situ from triphenylphosphine and trifluoromethanesulfonic or trifluoroacetic acid. The structure of the synthesized phosphonium salts was determined by NMR spectroscopy and X-ray analysis.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    N. R. Khasiyatullina, A. M. Vazykhova, Yu. K. Voronina & V. F. Mironov

Authors
  1. N. R. Khasiyatullina
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  2. A. M. Vazykhova
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  3. Yu. K. Voronina
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  4. V. F. Mironov
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Correspondence to N. R. Khasiyatullina.

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Original Russian Text © N.R. Khasiyatullina, A.M. Vazykhova, Yu.K. Voronina, V.F. Mironov, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 9, pp. 1451–1457.

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Khasiyatullina, N.R., Vazykhova, A.M., Voronina, Y.K. et al. Reaction of 1,4-benzoquinones with PH-phosphonium salts. Russ J Gen Chem 87, 1934–1940 (2017). https://doi.org/10.1134/S1070363217090079

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  • DOI: https://doi.org/10.1134/S1070363217090079

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