Russian Journal of General Chemistry

, Volume 87, Issue 8, pp 1759–1765 | Cite as

1'-Phthalazinylhydrazone of acetylferrocene: Structure, properties, and complexing ability

  • S. I. Levchenkov
  • E. A. Raspopova
  • A. N. Morozov
  • K. Yu. Suponitskii
  • Yu. O. Tkacheva
  • L. D. Popov
Article

Abstract

1'-Phthalazinylhydrazone of acetylferrocene (HL) and copper(II) and nickel(II) complexes on its basis [CuL2] and [NiL2] have been synthesized and investigated. The structure of the hydrazine was determined by X-ray diffraction analysis. Quantum-chemical simulation of the tautomerism of the hydrazone was performed.

Keywords

ferrocene phthalazinylhydrazones electron spectroscopy tautomerism density functional theory complex formation 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • S. I. Levchenkov
    • 1
    • 2
  • E. A. Raspopova
    • 2
  • A. N. Morozov
    • 2
  • K. Yu. Suponitskii
    • 3
  • Yu. O. Tkacheva
    • 2
  • L. D. Popov
    • 2
  1. 1.Southern Scientific Center of Russian Academy of SciencesRostov-on-DonRussia
  2. 2.Southern Federal UniversityRostov-on-DonRussia
  3. 3.A.N. Nesmeyanov Institute of Organoelemental Compounds of Russian Academy of SciencesMoscowRussia

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