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β-Bromo-substituted palladium(II) tetraphenylporphyrins. Synthesis and spectral properties

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Abstract

Bromination of (5,10,15,20-tetraphenylporphyrinato)palladium(II) and [5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinato]palladium(II) with N-bromosuccinimide in chloroform–dimethylformamide and chloroform afforded mono-, tetra-, and octabromo derivatives substituted at the pyrrole rings. The products were identified by electronic absorption, 1H NMR, and mass spectra and elemental analyses.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    N. V. Chizhova, O. V. Mal’tseva, N. Zh. Mamardashvili & O. I. Koifman

  2. Ivanovo State University of Chemistry and Technology, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    O. I. Koifman

  3. Research Institute of Macroheterocyclic Chemistry, Ivanovo State University of Chemistry and Technology, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    O. I. Koifman

Authors
  1. N. V. Chizhova
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  2. O. V. Mal’tseva
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  3. N. Zh. Mamardashvili
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  4. O. I. Koifman
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Corresponding author

Correspondence to N. V. Chizhova.

Additional information

Original Russian Text © N.V. Chizhova, O.V. Mal’tseva, N.Zh. Mamardashvili, O.I. Koifman, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1188–1191.

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Chizhova, N.V., Mal’tseva, O.V., Mamardashvili, N.Z. et al. β-Bromo-substituted palladium(II) tetraphenylporphyrins. Synthesis and spectral properties. Russ J Gen Chem 87, 1580–1583 (2017). https://doi.org/10.1134/S1070363217070222

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  • DOI: https://doi.org/10.1134/S1070363217070222

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