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Thermal stability of chlorophyll a derivatives containing hydrophilic groups

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Abstract

Trends in thermal stability of aromatic macroheterocycles based of pheophorbide a and chlorin e 6 containing hydrophilic groups have been revealed by means of thermogravimetric analysis at 298–1223 K under inert atmosphere. Methylpheophorbide a and 13(1)-N-methylamide of chlorin e 6 are the most stable, the decomposition onset temperature being t o 351 and 333°С. Their functional substitution leads t o the reduction in thermal stability. Depending on the macrocycle structure the decrease in t o can reach 20–200°С.

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Authors and Affiliations

  1. Research Institute of Macroheterocyclic Chemistry, Ivanovo State University of Chemistry and Technology, pr. Sheremetevskii 7, Ivanovo, 153000, Russia

    D. B. Berezin, V. V. Makarov & Yu. V. Romanenko

  2. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    S. S. Guseinov & A. V. Kustov

  3. Institute of Chemistry, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Russia

    I. S. Khudyaeva, O. M. Startseva & D. V. Belykh

Authors
  1. D. B. Berezin
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  2. V. V. Makarov
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  3. S. S. Guseinov
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  4. Yu. V. Romanenko
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  5. I. S. Khudyaeva
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  6. O. M. Startseva
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  7. D. V. Belykh
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  8. A. V. Kustov
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Correspondence to D. B. Berezin.

Additional information

Original Russian Text © D.B. Berezin, V.V. Makarov, S.S. Guseinov, Yu.V. Romanenko, I.S. Khudyaeva, O.M. Startseva, D.V. Belykh, A.V. Kustov, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1164–1168.

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Berezin, D.B., Makarov, V.V., Guseinov, S.S. et al. Thermal stability of chlorophyll a derivatives containing hydrophilic groups. Russ J Gen Chem 87, 1557–1561 (2017). https://doi.org/10.1134/S1070363217070192

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  • DOI: https://doi.org/10.1134/S1070363217070192

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