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Effect of halogenation features on the stability of Zinc(II) complexes with monoiodo- and dibromodipyrromethenes

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Abstract

The complex formation of zinc(II) acetate with monoiodo- and dibromo-substituted dipyrromethenes in DMF at 298.15 K were studied by means of spectrophotometric titration. It was found that the process involves consecutive formation of heteroligand [ZnLOAc] and homoligand [ZnL2] complexes. The thermodynamic stability of halogenated zinc(II) dipyrrolylmethenates [ZnL2] was studied.

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Authors and Affiliations

  1. G.A. Krestov Institution of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    E. N. Nuraneeva, G. B. Guseva & E. V. Antina

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  1. E. N. Nuraneeva
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  2. G. B. Guseva
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  3. E. V. Antina
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Correspondence to G. B. Guseva.

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Original Russian Text © E.N. Nuraneeva, G.B. Guseva, E.V. Antina, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1157–1163.

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Nuraneeva, E.N., Guseva, G.B. & Antina, E.V. Effect of halogenation features on the stability of Zinc(II) complexes with monoiodo- and dibromodipyrromethenes. Russ J Gen Chem 87, 1550–1556 (2017). https://doi.org/10.1134/S1070363217070180

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  • DOI: https://doi.org/10.1134/S1070363217070180

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