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Light-induced formation of nitroxyl radicals by organic Bi(V) compounds in the presence of 2-methyl-2-nitrosopropane and C-phenyl-N-tert-butylnitrone

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Abstract

The organic bismuth compounds Ph3Bi(O2CCH=CHCH3)2 and Ph3Bi(O2CEt)2 decompose under scattered light in the presence of spin traps (2-methyl-2-nitrosopropane and C-phenyl-N-tert-butylnitrone) in organic solvents (acetonitrile, benzene, toluene) to form adducts of phenyl radicals with the traps.

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Authors and Affiliations

  1. Lobachevskii Nizhny Novgorod State University, pr. Gagarina 23, Nizhny Novgorod, Russia

    A. V. Gushchin, O. S. Kalistratova, A. I. Maleeva, V. A. Dodonov, D. Yu. Kosov & D. N. Emel’yanov

  2. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    V. A. Kuropatov

Authors
  1. A. V. Gushchin
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  2. O. S. Kalistratova
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  3. A. I. Maleeva
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  4. V. A. Dodonov
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  5. D. Yu. Kosov
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  6. D. N. Emel’yanov
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  7. V. A. Kuropatov
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Corresponding author

Correspondence to A. V. Gushchin.

Additional information

Original Russian Text © A.V. Gushchin, O.S. Kalistratova, A.I. Maleeva, V.A. Dodonov, D.Yu. Kosov, D.N. Emel’yanov, V.A. Kuropatov, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1154–1156.

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Gushchin, A.V., Kalistratova, O.S., Maleeva, A.I. et al. Light-induced formation of nitroxyl radicals by organic Bi(V) compounds in the presence of 2-methyl-2-nitrosopropane and C-phenyl-N-tert-butylnitrone. Russ J Gen Chem 87, 1547–1549 (2017). https://doi.org/10.1134/S1070363217070179

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  • DOI: https://doi.org/10.1134/S1070363217070179

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