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Features of reactions of (E)-[(2-aroyl)ethenyl]triphenylphosphonium bromides with binucleophiles

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Abstract

Reactions of (E)-[(2-aroyl)ethenyl]triphenylphosphonium bromides with hydroxylamine hydrochloride resulted in the formation of oximes undergoing α-phenyl migration when reacted with aqueous alkali. Reaction of these salts with hydrazine hydrochloride and o-phenylenediamine yielded [(2-aroyl)ethyl]triphenyl-phosphonium salts and phosphorus-substituted quinoxalines, respectively.

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Authors and Affiliations

  1. Institute of Organic Chemistry of the Scientific and Technological Center of the Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia, pr. Azatutyan 26, Yerevan, 0014, Armenia

    R. Dzh. Khachikyan, Z. G. Ovakimyan, G. A. Panosyan, R. A. Tamazyan & A. G. Ayvazyan

Authors
  1. R. Dzh. Khachikyan
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  2. Z. G. Ovakimyan
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  3. G. A. Panosyan
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  4. R. A. Tamazyan
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  5. A. G. Ayvazyan
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Corresponding author

Correspondence to R. Dzh. Khachikyan.

Additional information

Original Russian Text © R.Dzh. Khachikyan, Z.G. Ovakimyan, G.A. Panosyan, R.A. Tamazyan, A.G. Ayvazyan, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1110–1116.

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Khachikyan, R.D., Ovakimyan, Z.G., Panosyan, G.A. et al. Features of reactions of (E)-[(2-aroyl)ethenyl]triphenylphosphonium bromides with binucleophiles. Russ J Gen Chem 87, 1503–1509 (2017). https://doi.org/10.1134/S1070363217070106

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  • DOI: https://doi.org/10.1134/S1070363217070106

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