Russian Journal of General Chemistry

, Volume 87, Issue 7, pp 1490–1494 | Cite as

Reaction of methyl 2,4-dioxobutanoates with tetracyanoethylene

  • V. P. Sheverdov
  • M. A. Mar’yasov
  • V. V. Davydova
  • O. E. Nasakin
  • P. V. Dorovatovskii
  • V. N. Khrustalev
Article
  • 24 Downloads

Abstract

Reaction of methyl 2,4-dioxobutanoates with tetracyanoethylene yielded methyl 3-acyl-4-cyano-5-(dicyanomethylene)-2-hydroxy-2,5-dihydro-1H-pyrrole-2-carboxylates. X-Ray diffraction data showed that 3-acyl-4-cyano-5-(dicyanomethylene)-2-hydroxy-2,5-dihydro-1H-pyrrole-2-carboxylic acid methyl esters can form supramolecular structures with one-dimensional channels which make possible inclusion of large organic and bioorganic molecules.

Keywords

methyl 2,4-dioxobutanoates tetracyanoethylene pyrroles 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • V. P. Sheverdov
    • 1
  • M. A. Mar’yasov
    • 1
  • V. V. Davydova
    • 1
  • O. E. Nasakin
    • 1
  • P. V. Dorovatovskii
    • 2
  • V. N. Khrustalev
    • 3
    • 4
  1. 1.Ul’yanov Chuvash State UniversityCheboksaryRussia
  2. 2.National Research Center “Kurchatov Institute,”MoscowRussia
  3. 3.Russian People’s Friendship UniversityMoscowRussia
  4. 4.Nesmeyanov Institute of Organoelemental CompoundsRussian Academy of SciencesMoscowRussia

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