Abstract
Photolytic decomposition of the complex [Co(NH3)5(H2O)](ClO4)3 under the action of a laser with a wavelength of 355 nm, which is resonant in energy to the energy of the (1 A 1g → 1 T 2g ) d–d transition, was studied. Decomposition of the complex is accompanied by a release of ammonia with its subsequent oxidation to nitrogen oxides and by partial cobalt reduction with the formation of the mixed cobalt(II, III) oxide Co3O4.
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References
Ageev, M.V., Egorov, V.N., Katalkina, V.A., Petrov, V.N., and Chuchupal, L.N., RF Patent 2261851 C1, 2005.
Smirnov, A.V., Ilyushin, M.A., and Tselinskii, I.V., Russ. J. Appl. Chem., 2004, vol. 77, no. 5, p. 794. doi 10.1023/B:RJAC.0000038815.59138.f3
Matias, R. and Pachman, J., Primary Explosives, Berlin, Heidelberg: Springer, 2013
Ahmad, S.R. and Cartwright, M., Laser Ignition of Energetic Materials, Oxford John Wiley & Sons, 2014.
Lever, A.B.P., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1984, 2nd ed.
Tang, C.W., Wang, C.B., and Chien, S.H., Thermochim. Acta, 2008, vol. 473, p. 68. doi 10.1016/j.tca.2008.04.015
Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York John Wiley, 1986.
Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Hoboken: John Wiley, 2009, 6th ed.
Rudolph, W.W. and Irmer, G., Dalton Trans., 2013, vol. 42, p. 14460. doi 10.1039/C3DT51493E
Larkin, P.J., IR and Raman Spectroscopy, Principles and Spectral Interpretation, Amsterdam Elsevier Inc., 2011.
Tarasevich, B.N., IK spektry osnovnykh klassov organicheskikh soedinenii. Spravochnye materialy (IR Spectra of Main Classes of Organic Compounds. Reference Materials), Moscow Mosk. Gos. Univ., 2012.
Kloprogge, J.Th., Wharton, D., Hickey, L., and Frost, R.L., Am. Mineral., 2002, vol. 87, nos. 5–6, p. 623.
Mikuli, E., Migdal-Mikuli, A., Gorska, N., Wrobel, S., Sciesinski, J., and Sciesinska, E., J. Mol. Struct., 2003, vols. 651–653, p. 519. doi 10.1016/S0022-2860(03)00114-5
Hadjiev, V.G., Iliev, M.N., and Vergilov, I.V., J. Phys. (C), 1988, vol. 21, p. 199. doi 10.1088/0022-3719/21/7/007
Hexamminecobalt(III) Chloride. http://www.sigmaaldrich. com/spectra/rair/RAIR003720.PDF.
Rudolph, W.W. and Pye, C.C., Phys. Chem. Chem. Phys., 2002, vol. 4, p. 4319. doi 10.1039/b202567c
Brown, M.E., Dollimore, D., and Galwey, A.K., Reactions in the Solid State, Amsterdam: Elsevier, 1980, vol. 22.
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Original Russian Text © G.O. Abdrashitov, A.O. Aver’yanov, M.D. Bal’makov, M.A. Ilyushin, A.S. Tverjanovich, Yu.S. Tver’yanovich, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1057–1061.
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Abdrashitov, G.O., Aver’yanov, A.O., Bal’makov, M.D. et al. Decomposition of pentaammineaquacobalt(III) perchlorate under laser radiation action. Russ J Gen Chem 87, 1451–1455 (2017). https://doi.org/10.1134/S1070363217070015
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DOI: https://doi.org/10.1134/S1070363217070015